| 68851-48-9

• CAS: 68851-48-9
• 化学式: C₅₀H₄₄Cl₂P₄Pt₂S
• 分子量: 1261.93
• InChiKey: AJDNSMOCEPZKNT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 H₂O₂ 、 CH₃ReO₃ 作用下， 以 not given 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Two Routes to Bis(μ-diphenylphosphino)methane Diplatinum Halides Bridged by Sulfur Monoxide

  摘要：

  The new compounds Pt-2(mu-diphenylphosphinomethane)(2)(mu-SO)X-2, with X = Cl and I, have been prepared and characterized. One route was to use Pt-2(mu-dppm)(2)X-2 to trap the sulfur monoxide Liberated from decomposition of a sultine intermediate formed from the oxidation. of a thioketone sulfoxide with hydrogen peroxide, catalyzed by CH3ReO3 (MTO). The second and preferable route consists of the oxidation of Pt-2(mu-dppm)(2)(mu-S)X-2 With hydrogen peroxide, catalyzed by CH3ReO3 (MTO). The X-ray structural analysis of Pt-2(mu-dppm)(2)(mu-SO)Cl-2 showed that it has an "A-frame" structure in. which the bridge sulfur atom has the geometry of a distorted trigonal bipyramid.

  DOI：

  10.1021/om9905815
• 作为产物：
  描述：

  1,2,3,4,5,6,7,8-八硫杂环辛烷 、 dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Muralidharan; Espenson, James H.; Ross, Scott A., Inorganic Chemistry, 1986, vol. 25, # 15, p. 2557 - 2562

  摘要：

  DOI：

文献信息

• Multinuclear NMR investigations of bis-μ-[bis-(diphenylphosphino)methane] bis(trichlorostannio)-diplatinum(PtPt) and Bis-μ-[bis(diphenylphosphino) methane] chloro(trichlorostannio)diplatinum(PtPt); Observation of the largest recorded 3J coupling constant
  作者：Martin C. Grossel、Roger P. Moulding、Kenneth R. Seddon

  DOI：10.1016/s0020-1693(00)90352-9

  日期：1982.1