| 1259516-93-2

• CAS: 1259516-93-2
• 化学式: C₆₅H₁₁NO
• 分子量: 821.808
• InChiKey: ZBAGPKXDVHDZOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,3-二甲基-2-丁烯 、 bis-azafullerene 在 氧气 、 对甲苯磺酸 作用下， 以 邻二氯苯 为溶剂， 以11%的产率得到
  参考文献：
  名称：

  Exploring the photoinduced electron transfer reactivity of aza[60]fullerene iminium cation

  摘要：

  Photolysis of (C59N)(2) solutions in the presence of neutral pi-donors, such as arenes and electron-rich alkenes leads to a series of novel aza[60]fullerene monoadducts. The key step of the reaction involves a photoinduced electron transfer from the donor molecule to the iminium cation of aza[60]fullerene, followed by radical coupling of the resulting aza[60]fullerenyl radical with an intermediate stabilized radical derived from the substrate. This type of reactivity has been proven efficient with arenes having oxidation potential higher than about 1.5 V. Simple olefins, such as tri- and tetra-methylethylene, as well as cyclohexene, can also participate in this kind of photoinduced electron transfer-initiated reaction with C59N+, affording the corresponding aza[60]fullerene derivatives. In the case of 2-methoxyprop-1-ene, 2,4-hexadiene, and beta,beta-dimethylstyrene, [2+2] cycloaddition reactions with the aza[60]fullerene carbon shell dominate, leading to a mixture of unidentified multiadducts. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.10.006