| 221151-90-2

• CAS: 221151-90-2
• 化学式: C₅₂H₇₀I₄Mo₂O₁₂P₄
• 分子量: 1710.51
• InChiKey: QOYZYZIRYXUZJD-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  MoI2(CO)3(MeCN)2 、 三异丙基亚磷酸酯 以 二氯甲烷 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Bimetallic bridged dppb {dppb=Ph2P(CH2)4PPh2} complexes [{MI2 (CO)3 (P (OR)3)}2 (μ-dppb)] (M=Mo, W): X-ray crystal structure of [{MoI2 (CO)3 (P (Oi Pr)3)}2 (μ-dppb)]

  摘要：

  Reaction of [MI2(CO)(3)(NCMe)(2)] with one equivalent of P(OR)(3) in CH2Cl2 at room temperature, followed by the in situ addition of half a molar equivalent of dppb {dppb = Ph2P(CH2)(4)PPh2} gave the bimetallic complexes [{MI2(CO)(3)(P(OR)(3))}(2)(mu-dppb)] (M=Mo. W, R=Me, Et, Pr-t, Bu-n; for M=W only, R=Ph) (1-->9) in good yield. The molybdenum complex [{MoI2 (CO)(3)(P((OPr)-Pr-i)(3))}(2) (mu-dppb)] (5) was crystallographically characterised and has crystallographic C-2 symmetry. Each molybdenum has a capped octahedral environment with P((OPr)-Pr-i)(3) in the capping position, three carbonyls in the capped face and the phosphorus from the bridging dppb ligand together with two iodines in the uncapped face. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00293-9