1,7-bis-ethynyl-m-carborane | 60839-32-9

• 英文名称: 1,7-bis-ethynyl-m-carborane
• 英文别名: 1,7-C2B10H10-1,7-(CCH)2
• CAS: 60839-32-9
• 化学式: C₆H₁₂B₁₀
• 分子量: 192.271
• InChiKey: GHQMGNTVGNRWAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans diiodobis(triethylphosphine)platinum(II) 、 1,7-bis-ethynyl-m-carborane 在 CuI 、 triethylamine 作用下， 以 三乙胺 、 甲苯 为溶剂， 以47%的产率得到1,7-(trans-(Pt(PEt3)2I)CC)2-m-C2B10H10
  参考文献：
  名称：

  Coordination-Driven Self-Assemblies with a Carborane Backbone

  摘要：

  The design and self-assembly of five new supramolecular complexes (a rectangle, a triangle, a hexagon, and two squares) are described. These assemblies incorporate carborane building blocks and were prepared in excellent yields (> 85%). The assemblies and building blocks were characterized with multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and elemental analysis. Isotopically resolved mass spectrometry data confirm the existence of the rectangle, triangle, and hexagon, and NMR data are consistent with the formation of all five assemblies. The X-ray structures of two linear carborane building blocks, 1,12-(4-C equivalent to C(C5H4N)(2)-p-C2B10H10 (1) and 1,12-(trans-(Pt(PEt3)(2)l)C equivalent to C)(2)-p-C2B10H10 (2), are reported: 1 is monoclinic, P2(1)/c, a = 10.6791(4) angstrom, b = 8.0091(14) angstrom, c = 11.6796(4) angstrom, beta = 107.8461(15)degrees, V = 950.89(5) angstrom(3), Z = 2; 2 is monoclinic, C2/c, a = 62.1128(10) angstrom, b = 22.0071(3) angstrom, c = 14.0494(2) angstrom, beta = 89.9411(8)degrees, V= 19204.4(5) A(3), Z = 16. Crystals of the linear linker 1 exhibit close pi-pi pyridine and pyridine-B (carborane) interactions, which are discussed.

  DOI：

  10.1021/ja053050i
• 作为产物：
  描述：

  1,7-bis(trans-β-chlorovinyl)-m-carborane 在 Iron(III) nitrate nonahydrate 氯化铵 、 sodium amide 作用下， 以 氨 为溶剂， 以75%的产率得到1,7-bis-ethynyl-m-carborane
  参考文献：
  名称：

  Preparation of 1-ethynyl-o, m?, and p-carboranes from carboranylcopper compounds

  摘要：

  DOI：

  10.1007/bf00956611

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B Comp.SVol.1/3, 13.18.4.2, page 233 - 240
  作者：

  DOI：——

  日期：——
• Zakharkin, L. I.; Kovredov, A. I., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1976, p. 1953
  作者：Zakharkin, L. I.、Kovredov, A. I.

  DOI：——

  日期：——