| 92266-60-9

• CAS: 92266-60-9
• 化学式: C₄₉H₃₁Ag₆Fe₃O₁₂P₃
• 分子量: 1719.45
• InChiKey: ODQMRLIBUBGKCH-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Collman's reagent 、 以 四氢呋喃 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Synthesis and structural characterisation of [Ag₆{Fe(CO)₄}₃{(Ph₂P)₃CH}]: a distorted tricapped octahedral silver–iron cluster

  摘要：

  [Ag6{Fe(CO4)}3{(Ph2P)3CH}] has been synthesised from [Fe(CO)4]2– and [Ag3Cl3{(Ph2P)3CH}] in tetrahydrofuran and shown to have a distorted tricapped octahedral cluster geometry by a single crystal X-ray crystallographic determination; the capping positions are occupied by the iron atoms and the tripodal ligand is co-ordinated to three silver atoms on a face of the octahedron.

  DOI：

  10.1039/c39840000586