[Zn(ferrocenylthiocarboxylato)2(2,2'-bipyridine)] | 1052259-98-9

• 英文名称: [Zn(ferrocenylthiocarboxylato)2(2,2'-bipyridine)]
• CAS: 1052259-98-9
• 化学式: C₃₂H₂₆Fe₂N₂O₂S₂Zn
• 分子量: 711.787
• InChiKey: PZNSBKQPYKTEEH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 sodium ferrocenyl thiocarboxylate 、 zinc(II) acetate dihydrate 以 甲醇 为溶剂， 以66%的产率得到[Zn(ferrocenylthiocarboxylato)2(2,2'-bipyridine)]
  参考文献：
  名称：

  Syntheses and characterization of ferrocenylthiocarboxylate-containing coordination compounds for nonlinear optics

  摘要：

  Four metal-organic coordination compounds containing ferrocenylthiocarboxylate components, [Cd-2(eta(2)-SOCFc) (2)(eta(1)-mu(2)-SOCFc)(2)(4,4'-bpy)](n) (1), [Cd(SOCFc)(2)(tmp)](n) (tmp = 4,40-trimethylene-dipyridine) (2) [Zn(SOCFc)(2)(2,2'-bpy)] (3), and {[Hg(SOCFc)(2)(phen)] center dot (0.5CH(3)OH)} (4) (Fc = (eta(5)-C5H5) Fe(eta(5)-C5H4)), have been prepared in search of good nonlinear optical (NLO) materials. Investigation of the NLO properties shows that Hg-containing compound 4 exhibits very strong third-order NLO absorptive and refractive effects. The NLO absorptive coefficient alpha(2) value (2.11 x 10(10) mW (1)) is larger than those of all the reported ferrocenylcarboxylate-containing coordination compounds and comparable to the well-performing Hg-containing complexes. Additionally, we further analyzed their NLO behaviors through studying electrochemical properties of the four compounds. (C) 2008 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2008.05.017