dimethylaluminium tert-butyl sulfide | 60699-27-6

• 英文名称: dimethylaluminium tert-butyl sulfide
• 英文别名: dimethylaluminum t-butylsulfide；Dimethylaluminium tert-butyl thiolate；Tert-butylsulfanyl(dimethyl)alumane
• CAS: 60699-27-6
• 化学式: C₆H₁₅AlS
• 分子量: 146.233
• InChiKey: MAMLZTGFRVBGIG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.77
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  selenobenzoic acid O-methyl ester 、 dimethylaluminium tert-butyl sulfide 以 甲苯 为溶剂， 以56%的产率得到
  参考文献：
  名称：

  Murai, Toshiaki; Mizutani, Tomoyoshi; Ogino, Yuji, Phosphorus, Sulfur and Silicon and the Related Elements, 1998, vol. 136, p. 561 - 564

  摘要：

  DOI：

文献信息

• The first stereocontrolled synthesis of diequatorial bislactone furofuran lignans having two different aryl groups: A synthesis of methyl 4, 8-dioxopiperitol
  作者：Shin-ichi Yoshida、Tsuyoshi Ogiku、Hiroshi Ohmizu、Tameo Iwasaki

  DOI：10.1016/0040-4039(95)00080-v

  日期：1995.2

  Methyl 4, 8-dioxopiperitol (1), a representative example of the diequatorial bislactone furofuran lignans having two different aryl groups, was synthesized based on the stereocontrolled aldol reaction of the acid anhydride3 and veratral.

  基于酸酐3和芳族化合物的立体控制的羟醛反应，合成了甲基4、8-二氧戊哌醇（1），其为具有两个不同芳基的二水合双内酯呋喃呋喃木脂素的代表性实例。
• First Stereocontrolled Syntheses of Unsymmetrically Substituted Bislactone Lignans:  Stereocontrolled Syntheses of Four Possible Isomers of Methyl 4,8-Dioxoxanthoxylol
  作者：Shin-ichi Yoshida、Tsuyoshi Ogiku、Hiroshi Ohmizu、Tameo Iwasaki

  DOI：10.1021/jo961733y

  日期：1997.3.1

  An efficient method for stereocontrolled syntheses of the unsymmetrically substituted bislactone subgroup of the furofuran lignan has been developed based on a stereoselective aldol reaction of the acid anhydride 8 or 9 and an aromatic aldehyde employing methyl 4,8-dioxoxanthoxylol (1a), 4,8-dioxofargesin (1b), methyl 4,8-dioxopiperitol (2a) and their isomer 3a as the representative examples of the axial-equatorial 1, diequatorial 2, and diaxial 3 types of this series.
• Organoaluminum-promoted Beckmann rearrangement of oxime sulfonates
  作者：Keiji Maruoka、Tohru Miyazaki、Mamoru Ando、Yasushi Matsumura、Soichi Sakane、Kazunobu Hattori、Hisashi Yamamoto

  DOI：10.1021/ja00347a052

  日期：1983.5
• Synthesis of crobarbatine acetate. A macrocyclic pyrrolizidine alkaloid ester
  作者：Jamin Huang、Jerrold Meinwald

  DOI：10.1021/ja00394a022

  日期：1981.2
• Dixon, Darren J.; Foster, Alison C.; Ley, Steven V., Journal of the Chemical Society. Perkin transactions I, 1999, # 12, p. 1631 - 1633
  作者：Dixon, Darren J.、Foster, Alison C.、Ley, Steven V.、Reynolds, Dominic J.

  DOI：——

  日期：——