[chlorobis(methyldiphenylphosphine)-1,4,7-triazacyclononane]ruthenium(II) chloride | 680183-76-0

• 英文名称: [chlorobis(methyldiphenylphosphine)-1,4,7-triazacyclononane]ruthenium(II) chloride
• 英文别名: [(tacn)RuCl(PMePh2)2]Cl
• CAS: 680183-76-0
• 化学式: C₃₂H₄₁ClN₃P₂Ru*Cl
• 分子量: 701.621
• InChiKey: ZEDSAYWDHYYZHM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichlorotetrakis(methyldiphenylphosphine)ruthenium(II) 、 1,4,7-三氮杂环壬烷 以 甲苯 为溶剂， 以41%的产率得到[chlorobis(methyldiphenylphosphine)-1,4,7-triazacyclononane]ruthenium(II) chloride
  参考文献：
  名称：

  Formation and structural studies of iron(III) and ruthenium(II) complexes of 1,4,7-triazacyclononane and N-monofunctionalised 1,4,7-triazacyclononane

  摘要：

  A series of 1,4,7-triazacyclononane derivatives of Fe(III) and Ru(II) have been investigated. The objective of this work was to investigate the effect of changing the functionality of a pendant group in order to create different Ru(II) and Fe(III) environments. From these studies, some interesting features are elucidated and different stacking properties arise due to the intra- and intermolecular X-(HCl)-Cl-... (X = O, N) interactions for the Fe(III) and Ru(II) complexes. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.07.002