di-μ(1,1)-azidobis[azido(2,5-dimethylpyridine)(formamide)]dicopper(II) | 191211-83-3

• 英文名称: di-μ(1,1)-azidobis[azido(2,5-dimethylpyridine)(formamide)]dicopper(II)
• CAS: 191211-83-3
• 化学式: C₁₆H₂₄Cu₂N₁₆O₂
• 分子量: 599.565
• InChiKey: MLZXPHZGKJBEOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 2,5-二甲基吡啶 、 sodium azide 、 formamide 以 水 、 formamide 、 丙酮 为溶剂， 生成 di-μ(1,1)-azidobis[azido(2,5-dimethylpyridine)(formamide)]dicopper(II)
  参考文献：
  名称：

  Polymeric complexes of copper(II) azide and 2,5-dimethylpyridine without and with solvent molecules. Synthesis, spectral and structural characterization of [Cu(2,5-dimethylpyridine) (N3)2]n and [Cu(2,5-dimethylpyridine) (N3)2(H2N-CHO)]2

  摘要：

  Catina di-mu(1,1)-azido[di-mu(1,1)-azidobis(2,5-dimethylpyridine(dicopper(II)] (1) and di-mu(1,1)-azidobis[azido(2,5-dimethylpyridine) (formamide)]dicopper(II) (2) were synthesized and characterized by spectroscopic and crystallographic methods. In the triclinic complex 1 the copper(II) centres are penta-coordinated by four nitrogen atoms from the azido ligands [Cu-N distances = 1.980(3)-2.249(4) Angstrom] and a fifth nitrogen from the organic molecule at a Cu-N bond length of 2.038(4) Angstrom. Both azido ligands function as mu(1,1) bridges to form chains of polyhedra along the crystallographic a axis. The dimeric molecule 2, which possesses a crystallographic inversion centre, contains both terminal and mu(1,1) bridging azido ligands. Each copper(II) atom is further coordinated by a 2,5-dimethylpyridine molecule [Cu-N = 1.998(4) Angstrom] and a formamide molecule via its carbonyl oxygen atom [Cu-O = 2.356(4) Angstrom] to give a distorted square pyramid. The IR absorption spectra reveal asymmetric azido ligands in both complexes, O-bonded formamide and hydrogen bonds as well, in 2. The solid and solution electronic spectra of both complexes exhibit more than one strong N-3(-) --> Cu-II charge-transfer transition band. The room-temperature EPR spectra of powdered samples and DMF solutions were recorded and discussed. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00537-2