| 207618-36-8

• CAS: 207618-36-8
• 化学式: C₂₄H₅₇AlN₇PSi₂
• 分子量: 557.89
• InChiKey: IGTNPTDMQGZIHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  劳森试剂 、 以 not given 为溶剂， 以63%的产率得到N-[[di(propan-2-yl)amino]-[2-(4-methoxyphenyl)-3-[6-methyl-1,3-bis(trimethylsilyl)-1,3,6,2-triazalumocan-2-yl]-2-sulfanylidene-1,3,4,2λ5-thiadiazaphosphol-5-yl]phosphanyl]-N-propan-2-ylpropan-2-amine
  参考文献：
  名称：

  The Azide-Nitrilimine Analogy in Aluminum Chemistry

  摘要：

  Tetracoordinate aluminum derivatives featuring an AlNNCR fragment are stable and possess a rich structural diversity, as exemplified by the nitrilimines 1 and 2, similar to that observed for the related azides. Compound 1 is the first structurally characterized six-membered AlN heterocycle in which the nitrogen and aluminum centers exhibit different coordination numbers. R=P(NiPr2 )2 ; R'=iBu; E=N, CR.

  DOI：

  10.1002/(sici)1521-3773(19980420)37:7<989::aid-anie989>3.0.co;2-1
• 作为产物：
  描述：

  [双(二异丙基氨基)膦基]重氮甲烷锂盐 、 [(Me3SiNCH2CH2)2NMe]AlCl 以 四氢呋喃 、 正己烷 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  The Azide-Nitrilimine Analogy in Aluminum Chemistry

  摘要：

  Tetracoordinate aluminum derivatives featuring an AlNNCR fragment are stable and possess a rich structural diversity, as exemplified by the nitrilimines 1 and 2, similar to that observed for the related azides. Compound 1 is the first structurally characterized six-membered AlN heterocycle in which the nitrogen and aluminum centers exhibit different coordination numbers. R=P(NiPr2 )2 ; R'=iBu; E=N, CR.

  DOI：

  10.1002/(sici)1521-3773(19980420)37:7<989::aid-anie989>3.0.co;2-1