η2-(2-acetylthien-3-yldithiocarboxylato)tetracarbonylmanganese | 516480-56-1

• 英文名称: η2-(2-acetylthien-3-yldithiocarboxylato)tetracarbonylmanganese
• CAS: 516480-56-1
• 化学式: C₁₁H₅MnO₅S₃
• 分子量: 368.294
• InChiKey: SKLAWMFJKHKDDO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二硫化碳 、 η(2)-(2-acetylthien-3-yl)tetracarbonylmanganese 以 二硫化碳 为溶剂， 以80%的产率得到η2-(2-acetylthien-3-yldithiocarboxylato)tetracarbonylmanganese
  参考文献：
  名称：

  Reactions of cyclomanganated complexes with carbon disulfide: routes to η2-aryldithiocarboxylate-Mn(CO)4 complexes and to the trithiocarbonate complex (μ3-CS3)2Mn4(CO)16

  摘要：

  Reaction of cyclomanganated aryl ketones with CS2 proceeds with insertion into the Mn-C bond to give eta(2)-dithiocarboxylato-Mn(CO)(4) compounds. With other cyclomanganated substrates such as that from Ph3P=S and also with Mn-2(CO)(10), CS2 gives (mu(3)-CS3)(2)Mn-4(CO)(16) with bridging trithiocarbonate ligands. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02024-7