1,4-bis((4-((5-N,N-bis(2-picolyl)amino-4,4-difluoro)-8-(4-tolyl)-4-bora-3a,4a- diaza-s-indacen-3-yl)ethynyl)phenylethynyl)-2,5-bis(dodecyloxy)benzene | 1255919-86-8

• 英文名称: 1,4-bis((4-((5-N,N-bis(2-picolyl)amino-4,4-difluoro)-8-(4-tolyl)-4-bora-3a,4a- diaza-s-indacen-3-yl)ethynyl)phenylethynyl)-2,5-bis(dodecyloxy)benzene
• 英文别名: 1,4-bis((4-((5-N,N-bis(2-picolyl)amino-4,4-difluoro)-8-(4-tolyl)-4-bora-3a,4a-diaza-s-indacen-3-yl)ethynyl)phenylethynyl)-2,5-bis(dodecyloxy)benzene
• CAS: 1255919-86-8
• 化学式: C₁₀₆H₁₀₆B₂F₄N₁₀O₂
• 分子量: 1649.69
• InChiKey: HKPUJRPULHCTAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-[N,N-di(2-picolyl)amino]-4,4-difluoro-3-[4-(ethynyl)phenylethynyl]-8-(p-tolyl)-4-bora-3a,4a-diaza-s-indacene 、 1,4-二(十二烷氧基)-2,5-二碘苯 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 20.0h， 以48%的产率得到1,4-bis((4-((5-N,N-bis(2-picolyl)amino-4,4-difluoro)-8-(4-tolyl)-4-bora-3a,4a- diaza-s-indacen-3-yl)ethynyl)phenylethynyl)-2,5-bis(dodecyloxy)benzene
  参考文献：
  名称：

  The synthesis and spectroscopic characterization of poly(p-phenylene ethynylene) with 3-connected BODIPY end groups

  摘要：

  A novel 3-connected BODIPY end-capped poly(p-phenylene ethynylene) and a matching model compound were synthesized by palladium-catalyzed cross-coupling reaction The structures were confirmed using (1)H NMR UV-vis spectrophotometry and fluorescence spectroscopy Both the polymer and the model compound showed absorption and emission bands characteristic for the BODIPY chromophore and the p-phenylene ethynylene linker However while upon excitation of the p-phenylene ethynylene linker energy transfer occurs for nearly 100% in the model compound it is only a minor decay channel of the singlet excited state of the p-phenylene ethynylene linker in the polymer (C) 2010 Elsevier Ltd All rights reserved

  DOI：

  10.1016/j.dyepig.2010.08.006