[manganese(μ-N,N'-propane-1,3-diylbis(3,5-chloro-salicylideneiminato))(μ-O)]2 | 261375-66-0

• 英文名称: [manganese(μ-N,N'-propane-1,3-diylbis(3,5-chloro-salicylideneiminato))(μ-O)]2
• CAS: 261375-66-0
• 化学式: C₃₄H₂₄Cl₈Mn₂N₄O₆
• 分子量: 978.088
• InChiKey: DVYBZUGUEGJXLT-XUPFZGOOSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  manganese(II) perchlorate hexahydrate 、 1,3-bis(3,5-dichlorosalicylidenamino)propane 在 NaOH 作用下， 以 甲醇 、 乙醇 为溶剂， 生成 [manganese(μ-N,N'-propane-1,3-diylbis(3,5-chloro-salicylideneiminato))(μ-O)]2
  参考文献：
  名称：

  Structural and photolytic studies on new mononuclear and binuclear manganese complexes containing Schiff base ligands. The crystal structure of [Mn(μ-3,5-Brsalpn)(μ-O)]2·2DMF

  摘要：

  Mononuclear and binuclear manganese Schiff base complexes containing substituted N,N ' -bis(salicylidene)propane-1,3-diamine ligands, H-2(Rsalpn) (R = 5-Br, 3,5-Br and 3,5-Cl), have been prepared and characterised by elemental analyses, IR and EPR spectroscopy, FAB and LDI-TOF mass spectrometry, cyclic voltammetry and magnetic measurements. The structure of [Mn(3,5-Brsalpn)O](2). 2DMF (5) has been determined by X-ray diffraction techniques. The compound has a dimeric structure with mu -oxo bridges and the ligand spanning both metal centres. The capacity of the complexes to oxidise phenothiazine and their ability to catalyse the photolysis of water have also been studied. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00719-7