| 1374146-92-5

• CAS: 1374146-92-5
• 化学式: C₁₁H₈O₆SW
• 分子量: 452.097
• InChiKey: AIUVOWSNIBPMAK-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  甲基戊酰氯 、 tricarbonyl(η5-cyclopentadienyl)(hydrogensulfido)tungsten 以 四氢呋喃 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  O-Alkylthiooxalato and dithiocarboxylato complexes of molybdenum and tungsten

  摘要：

  The hydrosulfido complexes CpM(CO)(3)SH (M = Mo, W) react with one equivalent of O-alkyl oxalyl chlorides, RO2CCOCI, to form the corresponding O-alkylthiooxalato complexes CpM(CO)(3)SCOCO2R [NI = Mo (1), W (2); R = Me (a), Et (b)]. The reaction of the hydrosulfido complexes with half equivalent of oxalyl or succinyl chlorides produces the bimetallic complexes [CpM(CO)(3)SCO](2) [M = Mo (3c), W (4c)] and [CpM(CO)(3)SCOCH2](2) [M = Mo (3d), W (4d)]. These new complexes have been characterized by elemental analysis, IR and NMR spectroscopy. The solid state structures of CpMo(CO)(3)SCOCO2CH3 (1a) and CpW(CO)(3)SCOCO2CH2CH3 (2b) were determined by X-ray crystal structure analysis. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.03.013