piperazinesilver(I) hexafluorophosphate | 1351934-11-6

• 英文名称: piperazinesilver(I) hexafluorophosphate
• CAS: 1351934-11-6
• 化学式: Ag*C₄H₁₀N₂*F₆P
• 分子量: 338.969
• InChiKey: JSUCHGXTFNCFOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  哌嗪 、 六氟磷酸银 以 乙腈 为溶剂， 以54%的产率得到piperazinesilver(I) hexafluorophosphate
  参考文献：
  名称：

  Synthesis and structure of coordination polymer compounds of AgReO4 and AgPF6 with piperazine

  摘要：

  Coordination polymers [Ag(C4H10N2)]ReO4 (I) and [Ag(C4H10N2)]PF6 (II) (C4H10N2 is piperazine, Ppz) were synthesized and their structures were determined. Crystals of compound I are monoclinic, space group P2(1)/c, a = 6.207(1) , b = 12.533(1) , c = 11.386(1) , beta = 93.41(1)A degrees, V = 884.2(2) (3), rho(calc) = 3.337 g/cm(3), Z = 4. Crystals of II are monoclinic, space group C2/m, a = 8.723(1) , b = 9.083(1) , c = 5.797(1) , beta = 95.07(1)A degrees, V = 457.5(1) (3), rho(calc) = 2.548 g/cm(3), Z = 2. Structure I contains polymer chains [Ag(Ppz)] (a) (+) . The silver atom is linked with two nitrogen atoms of the adjacent Ppz ligands to form a nearly linear fragment; the Ag-N-av distance is 2.173 , and the NAgN angle is 169.4(3)A degrees. The chains are linked with each other by weak interactions AgaEuro broken vertical bar O(ReO4) (2.643(8) ) and N-HaEuro broken vertical bar O hydrogen bonds. The structure of compound II also contains cationic polymer chains [Ag(Ppz)] (a) (+) . The Ag+ ion is located in the inversion center and has a linear coordination (Ag-N distance is 2.171(9) ). The central P atom of the octahedral fluorophos-phate ion is also located in the inversion center; the anion is slightly distorted and has no contacts with silver ions at a distance < 3.4 .

  DOI：

  10.1134/s0036023611110155