(η2-[60]-fullerene)(1,1'-bis(diphenylphosphino)ruthenocene)palladium(0) | 761405-13-4

• 英文名称: (η2-[60]-fullerene)(1,1'-bis(diphenylphosphino)ruthenocene)palladium(0)
• 英文别名: [(η2-C60)Pd((η5-Ph2PC5H4)2Ru)]
• CAS: 761405-13-4
• 化学式: C₉₄H₂₈P₂PdRu
• 分子量: 1426.69
• InChiKey: XWWRGVUWBAURQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(dibenzylideneacetone)dipalladium (0) 、 1,1'-bis(diphenylphosphino)ruthenocene 、 足球烯 以 not given 为溶剂， 生成 (η2-[60]-fullerene)(1,1'-bis(diphenylphosphino)ruthenocene)palladium(0)
  参考文献：
  名称：

  Comparison of electrochemical behavior of exohedral palladium complexes with [60]- and [70]-fullerenes and metallocene ligands

  摘要：

  Electronic structures of exohedral palladium complexes of [60]- and [70]-fullerenes with diphenylphosphinoferrocenyl, diphenylphosphinoruthenocenyl, and diphenylphosphinocymantrenyl ligands were studied by cyclic voltammetry and semiempirical quantum-chemical calculations. Probable sites of localization of electronic changes in the molecules of these complexes under electrochemical oxidation and reduction were determined.

  DOI：

  10.1023/b:rucb.0000037844.93864.3c

文献信息

• Synthetic and Structural Studies on the Transition-Metal Fullerene Complexes (η²-C₆₀)M[(η⁵-Ph₂PC₅H₄)₂Ru] and (η²-C₆₀)M[(η⁵-Ph₂PC₅H₄)₂Co]⁺(PF₆)^- (M = Pd, Pt) and the Related Compound {[<i>η</i>⁵-Ph₂P(O)C₅H₄]₂Co}⁺(PF₆)^-
  作者：Li-Cheng Song、Guang-Ao Yu、Fu-Hai Su、Qing-Mei Hu

  DOI：10.1021/om049667a

  日期：2004.8.1

  A toluene solution Of C-60 reacted with an equimolar quantity of M(dba)(2) (M = Pd, Pt; dba = dibenzylideneacetone) and (eta(5)-Ph2PC5H4)(2)Ru or with M(PPh3)(4) and (eta(5)-Ph2PC5H4)(2)Ru at room temperature to give the dinuclear transition-metal fullerene complexes (eta(2)-C-60)M [(eta(5)-Ph2PC5H4)(2)Ru] (1, M = Pd; 2, M = Pt), whereas the o-dichlorobenzene solution of C-60 reacted with an equimolar amount of M(dba)(2) and [(eta(5)-Ph2PC5H4)(2)Co](+)(PF6)(-) or with M(PPh3)(4) and [(eta(5)-Ph2PC5H4)(2)Co](+)(PF6)(-) under similar conditions to afford the dinuclear transition-metal fullerene complexes (eta(2)-C-60)M[(eta(5)-Ph2PC5H4)(2)Co](+)(PF6)(-) (3, M = Pd; 4, M = Pt). In addition, the related complex [eta(5)-Ph2P(O)C5H4](2)Co}(+)(PF6)(-) (5) was prepared by oxidation of [(eta(5)-Ph-2-PC5H4)(2)Co](+)(PF6)(-) with an excess amount of aqueous peracetic acid in acetone at room temperature. While 1-4 are the first examples of neutral and cationic dinuclear M/Ru and M/Co (M = Pd, Pt) fullerene complexes, 5 is the first organocobalt Cp complex containing a phosphoryl substituent. All products 1-5 have been fully characterized by elemental analysis, spectroscopy, and X-ray crystal diffraction techniques and, for 1 and 2, by cyclic voltammetry.