[(PhB(CH2PPh2)3-κ3P)Ru(acetonitrile)3]PF6 | 1255706-46-7

• 英文名称: [(PhB(CH2PPh2)3-κ3P)Ru(acetonitrile)3]PF6
• CAS: 1255706-46-7
• 化学式: C₅₂H₅₆BN₂P₄Ru*F₆P
• 分子量: 1089.77
• InChiKey: DNFLHNRUNAROIR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(PhB(CH2PPh2)3-κ3P)Ru(acetonitrile)3]PF6*2.25acetonitrile 、 三甲基膦 以 not given 为溶剂， 生成 [(PhB(CH2PPh2)3-κ3P)Ru(acetonitrile)3]PF6
  参考文献：
  名称：

  Synthesis and Reactivity of [(PhB(CH₂PPh₂)₃-κ³P)Ru(NCMe)₃]PF₆and Its Potential as a Transfer Hydrogenation Catalyst

  摘要：

  The acetonitrile ligands in [(PhB(CH2PPh2)(3)-kappa P-3)-Ru(NCMe)(3)]PF6 (1) (which contains a facially coordinated anionic tripodal phosphine ligand) are labile and are rapidly replaced by other ligands, although the steric profile of the phosphine ligand limits the size and the number of the incoming ligands. Complex 1 and some of its derivatives proved to be very efficient and rapid transfer hydrogenation precatalysts and yielded turnover frequencies (TOFs) greater than those typically observed for most other ruthenium-based catalysts.

  DOI：

  10.1021/om100552h