(Et3NH)[In(monoselenobenzoato)4]*H2O | 918947-15-6

• 英文名称: (Et3NH)[In(monoselenobenzoato)4]*H2O
• CAS: 918947-15-6
• 化学式: C₆H₁₆N*C₂₈H₂₀InO₄Se₄*H₂O
• 分子量: 971.339
• InChiKey: BOHRZGRQQBJMIU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (Et3NH)[In(monoselenobenzoato)4]*H2O 以 neat (no solvent) 为溶剂， 生成 indium(III) selenide
  参考文献：
  名称：

  New Heterobimetallic and Polymeric Selenocarboxylates Derived from [M(SeC{O}Ph)₄]^- (M = Ga and In) as Molecular Precursors for Ternary Selenides

  摘要：

  (Et3NH)[In(SeC{O}Ph)(4)]center dot H2O (1) along with heterobimetallic and polymeric metal selenocarboxylates, namely [NaGa( SeC{O}Ph)(4)](2), [K(MeCN)(2)Ga(SeC{O}Ph)(4)] (3), [NaIn(SeC{O}Ph)(4)] (4), [K(MeCN)(2)In(SeC{O}Ph)(4)] (5), [(Ph3P)(2)CuIn( SeC{O}Ph)(4)]center dot CH2Cl2 (6), and [(Ph3P)(2)AgIn(SeC{O}Ph)(4)]center dot CH2Cl2 (7), have been synthesized by incorporating either alkali metal ions (Na+ and K+) or group 11 metal ions (Cu(I) and Ag(I)) into the [M(SeC{O}Ph)(4)](-) anion. Crystal structures determined by X-ray crystallography indicate that 3 and 5 have one- dimensional coordination polymeric structures while 6 and 7 have an M(mu-Se)(2)In (M = Cu, Ag) core. The thermal decomposition of these compounds except 4 lead to the formation of the corresponding metal selenides as confirmed by thermogravimetric analysis and in some cases by powder X-ray diffraction studies.

  DOI：

  10.1021/ic0611286
• 作为产物：
  描述：

  [NaIn(monoselenobenzoato)4] 、 水 、 三乙胺盐酸盐 以 丙酮 、 乙腈 为溶剂， 以78%的产率得到(Et3NH)[In(monoselenobenzoato)4]*H2O
  参考文献：
  名称：

  New Heterobimetallic and Polymeric Selenocarboxylates Derived from [M(SeC{O}Ph)₄]^- (M = Ga and In) as Molecular Precursors for Ternary Selenides

  摘要：

  (Et3NH)[In(SeC{O}Ph)(4)]center dot H2O (1) along with heterobimetallic and polymeric metal selenocarboxylates, namely [NaGa( SeC{O}Ph)(4)](2), [K(MeCN)(2)Ga(SeC{O}Ph)(4)] (3), [NaIn(SeC{O}Ph)(4)] (4), [K(MeCN)(2)In(SeC{O}Ph)(4)] (5), [(Ph3P)(2)CuIn( SeC{O}Ph)(4)]center dot CH2Cl2 (6), and [(Ph3P)(2)AgIn(SeC{O}Ph)(4)]center dot CH2Cl2 (7), have been synthesized by incorporating either alkali metal ions (Na+ and K+) or group 11 metal ions (Cu(I) and Ag(I)) into the [M(SeC{O}Ph)(4)](-) anion. Crystal structures determined by X-ray crystallography indicate that 3 and 5 have one- dimensional coordination polymeric structures while 6 and 7 have an M(mu-Se)(2)In (M = Cu, Ag) core. The thermal decomposition of these compounds except 4 lead to the formation of the corresponding metal selenides as confirmed by thermogravimetric analysis and in some cases by powder X-ray diffraction studies.

  DOI：

  10.1021/ic0611286