摩熵化学
数据库官网
小程序
打开微信扫一扫
首页 分子通 化学资讯 化学百科 反应查询 关于我们
请输入关键词

(Et3NH)[In(monoselenobenzoato)4]*H2O | 918947-15-6

中文名称
——
中文别名
——
英文名称
(Et3NH)[In(monoselenobenzoato)4]*H2O
英文别名
——
(Et3NH)[In(monoselenobenzoato)4]*H2O化学式
CAS
918947-15-6
化学式
C6H16N*C28H20InO4Se4*H2O
mdl
——
分子量
971.339
InChiKey
BOHRZGRQQBJMIU-UHFFFAOYSA-K
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    None
  • 重原子数:
    None
  • 可旋转键数:
    None
  • 环数:
    None
  • sp3杂化的碳原子比例:
    None
  • 拓扑面积:
    None
  • 氢给体数:
    None
  • 氢受体数:
    None

反应信息

  • 作为反应物:
    描述:
    (Et3NH)[In(monoselenobenzoato)4]*H2O 以 neat (no solvent) 为溶剂, 生成 indium(III) selenide
    参考文献:
    名称:
    New Heterobimetallic and Polymeric Selenocarboxylates Derived from [M(SeC{O}Ph)4]- (M = Ga and In) as Molecular Precursors for Ternary Selenides
    摘要:
    (Et3NH)[In(SeC{O}Ph)(4)]center dot H2O (1) along with heterobimetallic and polymeric metal selenocarboxylates, namely [NaGa( SeC{O}Ph)(4)](2), [K(MeCN)(2)Ga(SeC{O}Ph)(4)] (3), [NaIn(SeC{O}Ph)(4)] (4), [K(MeCN)(2)In(SeC{O}Ph)(4)] (5), [(Ph3P)(2)CuIn( SeC{O}Ph)(4)]center dot CH2Cl2 (6), and [(Ph3P)(2)AgIn(SeC{O}Ph)(4)]center dot CH2Cl2 (7), have been synthesized by incorporating either alkali metal ions (Na+ and K+) or group 11 metal ions (Cu(I) and Ag(I)) into the [M(SeC{O}Ph)(4)](-) anion. Crystal structures determined by X-ray crystallography indicate that 3 and 5 have one- dimensional coordination polymeric structures while 6 and 7 have an M(mu-Se)(2)In (M = Cu, Ag) core. The thermal decomposition of these compounds except 4 lead to the formation of the corresponding metal selenides as confirmed by thermogravimetric analysis and in some cases by powder X-ray diffraction studies.
    DOI:
    10.1021/ic0611286
  • 作为产物:
    描述:
    [NaIn(monoselenobenzoato)4] 、 三乙胺盐酸盐丙酮乙腈 为溶剂, 以78%的产率得到(Et3NH)[In(monoselenobenzoato)4]*H2O
    参考文献:
    名称:
    New Heterobimetallic and Polymeric Selenocarboxylates Derived from [M(SeC{O}Ph)4]- (M = Ga and In) as Molecular Precursors for Ternary Selenides
    摘要:
    (Et3NH)[In(SeC{O}Ph)(4)]center dot H2O (1) along with heterobimetallic and polymeric metal selenocarboxylates, namely [NaGa( SeC{O}Ph)(4)](2), [K(MeCN)(2)Ga(SeC{O}Ph)(4)] (3), [NaIn(SeC{O}Ph)(4)] (4), [K(MeCN)(2)In(SeC{O}Ph)(4)] (5), [(Ph3P)(2)CuIn( SeC{O}Ph)(4)]center dot CH2Cl2 (6), and [(Ph3P)(2)AgIn(SeC{O}Ph)(4)]center dot CH2Cl2 (7), have been synthesized by incorporating either alkali metal ions (Na+ and K+) or group 11 metal ions (Cu(I) and Ag(I)) into the [M(SeC{O}Ph)(4)](-) anion. Crystal structures determined by X-ray crystallography indicate that 3 and 5 have one- dimensional coordination polymeric structures while 6 and 7 have an M(mu-Se)(2)In (M = Cu, Ag) core. The thermal decomposition of these compounds except 4 lead to the formation of the corresponding metal selenides as confirmed by thermogravimetric analysis and in some cases by powder X-ray diffraction studies.
    DOI:
    10.1021/ic0611286
点击查看最新优质反应信息