[(η6-C6H3Me3)Os(μ-H)2(μ-CHC6H3Me2-3,5)Os(η6-C6H3Me3)] | 95419-02-6

• 英文名称: [(η6-C6H3Me3)Os(μ-H)2(μ-CHC6H3Me2-3,5)Os(η6-C6H3Me3)]
• CAS: 95419-02-6
• 化学式: C₂₇H₃₆Os₂
• 分子量: 740.983
• InChiKey: JHQRSHSMRHZGRQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  锇 、 均三甲苯 以 neat (no solvent) 为溶剂， 以10%的产率得到[(η6-C6H3Me3)Os(μ-H)2(μ-CHC6H3Me2-3,5)Os(η6-C6H3Me3)]
  参考文献：
  名称：

  Arene–osmium chemistry: synthesis via osmium atoms of [Os(η⁶-C₆H₆)(η⁴-C₆H₆)],[{OS(η⁶-C₆H₃Me₃-1,3,5)}₂(µ-H)₂{µ-CH(C₆H₃Me₂-3,5)}], [{OS(η⁶-C₆H₃Me₃-1,3,5)}₂(µ-CHC₆H₃Me₂-3,5)], and [{OS(η⁶-C₆H₆)}₃{µ₃-(CH₂)₃CH}(µ-H)₃]. X-Ray crystal structure of [{Os(η⁶-C₆H₃Me₃-1,3,5)}₂(µ-CHC₆H₃Me₂-3,5)]

  摘要：

  DOI：

  10.1039/dt9860002477

文献信息

• (η⁶-Arene)osmium chemistry: crystal structure of [(η⁶-C₆H₃Me₃)Os(µ-CHC₆H₃Me₂-3,5)Os(η⁶-C₆H₃Me₃)]
  作者：Judith A. Bandy、Malcolm L. H. Green、Dermot O'Hare、Keith Prout

  DOI：10.1039/c39840001402

  日期：——

  Co-condensation of osmium atoms with benzene gives stable Os(η6-C6H6)(η4-C6H6) whereas co-condensation of osmium atoms with mesitylene forms the dimers[(η6-C6H3Me3)Os(µ-H)2(µ-CHC6H3Me2-3,5)Os(η6-C6H3Me3)] and [(η6-C6H3Me3)Os(µ-CHC6H3Me2-3,5)Os(η6-C6H3Me3)].