1,12-(trans-(Pt(PEt3)2I)CC)2-p-C2B10H10 | 865799-63-9

• 英文名称: 1,12-(trans-(Pt(PEt3)2I)CC)2-p-C2B10H10
• CAS: 865799-63-9
• 化学式: C₃₀H₇₀B₁₀I₂P₄Pt₂
• 分子量: 1306.86
• InChiKey: WQZZLMKEAPLQBY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,12-(trans-(Pt(PEt3)2I)CC)2-p-C2B10H10 、 silver nitrate 以 二氯甲烷 为溶剂， 生成 [1,12-(trans-Pt(PEt3)2CC)2-p-C2B10H10](NO3)2
  参考文献：
  名称：

  Coordination-Driven Self-Assemblies with a Carborane Backbone

  摘要：

  The design and self-assembly of five new supramolecular complexes (a rectangle, a triangle, a hexagon, and two squares) are described. These assemblies incorporate carborane building blocks and were prepared in excellent yields (> 85%). The assemblies and building blocks were characterized with multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and elemental analysis. Isotopically resolved mass spectrometry data confirm the existence of the rectangle, triangle, and hexagon, and NMR data are consistent with the formation of all five assemblies. The X-ray structures of two linear carborane building blocks, 1,12-(4-C equivalent to C(C5H4N)(2)-p-C2B10H10 (1) and 1,12-(trans-(Pt(PEt3)(2)l)C equivalent to C)(2)-p-C2B10H10 (2), are reported: 1 is monoclinic, P2(1)/c, a = 10.6791(4) angstrom, b = 8.0091(14) angstrom, c = 11.6796(4) angstrom, beta = 107.8461(15)degrees, V = 950.89(5) angstrom(3), Z = 2; 2 is monoclinic, C2/c, a = 62.1128(10) angstrom, b = 22.0071(3) angstrom, c = 14.0494(2) angstrom, beta = 89.9411(8)degrees, V= 19204.4(5) A(3), Z = 16. Crystals of the linear linker 1 exhibit close pi-pi pyridine and pyridine-B (carborane) interactions, which are discussed.

  DOI：

  10.1021/ja053050i
• 作为产物：
  描述：

  1,12-bis(ethynyl)-1,12-dicarba-closo-dodecaborane(12) 、 trans diiodobis(triethylphosphine)platinum(II) 在 CuI 、 triethylamine 作用下， 以 三乙胺 、 甲苯 为溶剂， 以48%的产率得到1,12-(trans-(Pt(PEt3)2I)CC)2-p-C2B10H10
  参考文献：
  名称：

  Coordination-Driven Self-Assemblies with a Carborane Backbone

  摘要：

  The design and self-assembly of five new supramolecular complexes (a rectangle, a triangle, a hexagon, and two squares) are described. These assemblies incorporate carborane building blocks and were prepared in excellent yields (> 85%). The assemblies and building blocks were characterized with multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and elemental analysis. Isotopically resolved mass spectrometry data confirm the existence of the rectangle, triangle, and hexagon, and NMR data are consistent with the formation of all five assemblies. The X-ray structures of two linear carborane building blocks, 1,12-(4-C equivalent to C(C5H4N)(2)-p-C2B10H10 (1) and 1,12-(trans-(Pt(PEt3)(2)l)C equivalent to C)(2)-p-C2B10H10 (2), are reported: 1 is monoclinic, P2(1)/c, a = 10.6791(4) angstrom, b = 8.0091(14) angstrom, c = 11.6796(4) angstrom, beta = 107.8461(15)degrees, V = 950.89(5) angstrom(3), Z = 2; 2 is monoclinic, C2/c, a = 62.1128(10) angstrom, b = 22.0071(3) angstrom, c = 14.0494(2) angstrom, beta = 89.9411(8)degrees, V= 19204.4(5) A(3), Z = 16. Crystals of the linear linker 1 exhibit close pi-pi pyridine and pyridine-B (carborane) interactions, which are discussed.

  DOI：

  10.1021/ja053050i