| 1448007-97-3

• CAS: 1448007-97-3
• 化学式: BF₄*C₃₃H₂₄NOP₂PdS₂
• 分子量: 769.864
• InChiKey: MMFVHIAKMMAMFO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  一氧化碳 、 以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Influence of the Ligand Backbone in Pincer Complexes: Indenediide-, Indolyl-, and Indenyl-Based SCS Palladium Complexes

  摘要：

  A new pincer ligand featuring an indolyl backbone was prepared and coordinated to palladium. The properties of related indenediide-, indenyl-, and indolyl-based complexes have been compared by spectroscopic and structural means. Modulation of the ligand backbone was shown to significantly influence the electron density at Pd. Its impact on catalytic performance has been illustrated in the Pd-catalyzed imine allylation. The higher the electron density at Pd, the more active the SCS pincer complex.

  DOI：

  10.1021/om400464j