[(Ph3PCHCOC6H4-4-Cl)mercury(II)dichloride]2 | 1042769-31-2

• 英文名称: [(Ph3PCHCOC6H4-4-Cl)mercury(II)dichloride]2
• CAS: 1042769-31-2
• 化学式: C₅₂H₄₀Cl₆Hg₂O₂P₂
• 分子量: 1372.73
• InChiKey: AFGRMMMLUQFKCA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(Ph3PCHCOC6H4-4-Cl)mercury(II)dichloride]2 、 二甲基亚砜 以 二甲基亚砜 为溶剂， 以96%的产率得到[(Ph3PCHCOC6H4-4-Cl)mercury(II)(chloride)2(DMSO)]
  参考文献：
  名称：

  Structural, theoretical and multinuclear NMR study of mercury(II) complexes of phosphorus ylides: Mono and binuclear complexes

  摘要：

  Reaction of phosphorus ylide Ph(3)PCHC(O)c(6)H(4)Cl (Y(1)) with HgX(2) (X = Cl, Br and I) and ylide (p-tolyl)(3)PCHC(O)CH(3) (Y(2)) with HgI(2) in equimolar ratios using methanol as solvent leads to binuclear products. The bridge-splitting reaction of binuclear complex [(Y(1)) center dot HgCl(2)](2) by DMSO yields a mononuclear complex containing DMSO as ligand. O-coordination of DMSO is revealed by single crystal X-ray analysis in mononuclear complex of [(Y(1)) center dot HgCl(2) center dot DMSO]. C-coordination of ylides is confirmed by X-ray structure of binuclear complex [(Y(2)) center dot HgI(2)](2). Characterization of the obtained compounds was also performed by elemental analysis, IR, (1)H (31)P, and (13)C NMR. Theoretical studies on mercury(II) complexes of Y(1) show that formation of mononuclear complexes in DMSO soClution in which DMSO acts as a ligand, energetically is more favorable than that of binuclear complexes. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.03.009
• 作为产物：
  描述：

  4-chlorobenzoylmethylenetriphenylphosphorane 、 mercury dichloride 以 甲醇 为溶剂， 以56%的产率得到[(Ph3PCHCOC6H4-4-Cl)mercury(II)dichloride]2
  参考文献：
  名称：

  Structural, theoretical and multinuclear NMR study of mercury(II) complexes of phosphorus ylides: Mono and binuclear complexes

  摘要：

  Reaction of phosphorus ylide Ph(3)PCHC(O)c(6)H(4)Cl (Y(1)) with HgX(2) (X = Cl, Br and I) and ylide (p-tolyl)(3)PCHC(O)CH(3) (Y(2)) with HgI(2) in equimolar ratios using methanol as solvent leads to binuclear products. The bridge-splitting reaction of binuclear complex [(Y(1)) center dot HgCl(2)](2) by DMSO yields a mononuclear complex containing DMSO as ligand. O-coordination of DMSO is revealed by single crystal X-ray analysis in mononuclear complex of [(Y(1)) center dot HgCl(2) center dot DMSO]. C-coordination of ylides is confirmed by X-ray structure of binuclear complex [(Y(2)) center dot HgI(2)](2). Characterization of the obtained compounds was also performed by elemental analysis, IR, (1)H (31)P, and (13)C NMR. Theoretical studies on mercury(II) complexes of Y(1) show that formation of mononuclear complexes in DMSO soClution in which DMSO acts as a ligand, energetically is more favorable than that of binuclear complexes. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.03.009