| 915977-71-8

• CAS: 915977-71-8
• 化学式: C₁₅H₁₅CrNO₅
• 分子量: 341.284
• InChiKey: NYAIIVMLMQUSLI-HSDORCTDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 solid 为溶剂， 生成 chromium (VI) oxide
  参考文献：
  名称：

  Spectral and thermal studies of some chromium and molybdenum complexes with ONO donor Schiff bases

  摘要：

  Reactions of M(CO)(6), where M = Cr and Mo with Schiff bases prepared by the condensation of ethanolamine with either acetylacetone or benzoylacetone were investigated. The reactions of Cr(CO)(6) in benzene resulted in the formation of the tricarbonyl drivatives [Cr(CO)(3)(HL)], HL = acaceaH or baceaH. The HL proved to act as a tridentate ligand. The corresponding reactions with MO(CO)(6) in dioxane gave the oxo complexes [Mo2O6(HL)(2)] with HL was a bidentate. All prepared complexes were investigated using elemental analysis, IR, mass spectrometry, UV-vis absorption spectra and magnetic measurement. Thermal behaviors of the complexes were studied using by thermogravimetry (TG). Schemes for the thermal decomposition were proposed along with their mass fragmentation patterns. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2006.01.016
• 作为产物：
  描述：

  benzoylacetone mono-{2-hydroxy-ethylimine} 、 六羰基铬 以 苯 为溶剂， 以54%的产率得到
  参考文献：
  名称：

  Spectral and thermal studies of some chromium and molybdenum complexes with ONO donor Schiff bases

  摘要：

  Reactions of M(CO)(6), where M = Cr and Mo with Schiff bases prepared by the condensation of ethanolamine with either acetylacetone or benzoylacetone were investigated. The reactions of Cr(CO)(6) in benzene resulted in the formation of the tricarbonyl drivatives [Cr(CO)(3)(HL)], HL = acaceaH or baceaH. The HL proved to act as a tridentate ligand. The corresponding reactions with MO(CO)(6) in dioxane gave the oxo complexes [Mo2O6(HL)(2)] with HL was a bidentate. All prepared complexes were investigated using elemental analysis, IR, mass spectrometry, UV-vis absorption spectra and magnetic measurement. Thermal behaviors of the complexes were studied using by thermogravimetry (TG). Schemes for the thermal decomposition were proposed along with their mass fragmentation patterns. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2006.01.016