RuCl2(PPh3)2(4-(N,N-dimethylamino)pyridine)2 | 366452-44-0

• 英文名称: RuCl2(PPh3)2(4-(N,N-dimethylamino)pyridine)2
• CAS: 366452-44-0
• 化学式: C₅₀H₅₀Cl₂N₄P₂Ru
• 分子量: 940.897
• InChiKey: HDUCPLMUTFQMHH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-二甲氨基吡啶 、 tris(triphenylphosphine)ruthenium(II) chloride 以 二氯甲烷 为溶剂， 生成 RuCl2(PPh3)2(4-(N,N-dimethylamino)pyridine)2
  参考文献：
  名称：

  Electrochemical and spectroscopic studies on RuCl2(PPh3)2(N)2 and RuCl2(PPh3)2(N–N) complexes (N=pyridine derivatives and N–N=phenanthroline or bipyridine derivatives). X-ray structure of RuCl2(PPh3)2(phen)

  摘要：

  A series of RUCl2(PPh3)(2)(N)(2) and RUCl2(pPh(3))(2)(N - N) complexes were synthesized from RuCl2(PPh3)(3), (N)(2) = pyridine (py), 4-(N,N-dirnethylamino)pyridine (4-dmNpy), 4-tert-butylpyridine (4-' Bu-py), 4-methylpyridine (4-Mepy), 4-vinylpyridine (4-Vpy), 4-phenylpyridine (4-Phpy), isonicotinamide (4-CONH(2)py). 4-cyanopyridine (4-CNpy) N-N = 1,10-phenanthroline (phen), 2,2 ' -bipyridine (bipy), 2,2 ' -bipyridine-4,4 ' -dimethoxy (MeO-bipy), 2,2 ' -bipyridine-4,4 ' -dimethyl (Me-bipy), 2,2 ' -bipyridine-4,4 ' -dithiomethyl (MeS-bipy), 2,2 ' -bipyridine-4,4 ' -dichloro (Cl-bipy) and 2,2 ' -bipyridine-4,4 ' -dinitro (NO2-bipy). The complexes were characterized by elemental analysis, cyclic voltammetry and U-V-Vis, NMR and IR spectroscopies. The structure of the RUCl2(PPh3)(2)(phen) was established by single crystal X-ray crystallography. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00744-6