Bis-benzhydryl-nitroxid | 17419-92-0

• 英文名称: Bis-benzhydryl-nitroxid
• CAS: 17419-92-0
• 化学式: C₂₆H₂₂NO
• 分子量: 364.467
• InChiKey: QYQYCIZGKULOMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N-Dibenzhydryl-hydroxylamine 在 manganese(IV) oxide 作用下， 生成 Bis-benzhydryl-nitroxid
  参考文献：
  名称：

  Stable nitroxyl radicals with a hydrogen atom at ?-carbon atom of nitroxyl group

  摘要：

  Nitroxyl radicals containing the diphenylmethyl group as one of the substituents at the nitroxyl group are stable compounds that can be isolated in an individual state. N-(2-Hydroxy-3-methyl-2-phenylcyclohexyl)-N- diphenylmethylnitroxyl was characterized by X-ray diffraction analysis for the first time.

  DOI：

  10.1007/bf01433978

文献信息

• Spin trapping reactions with nitric oxides, I. Dialkyl nitroxides
  作者：Miklós Győr、Antal Rockenbauer、Ferenc Tüdős

  DOI：10.1016/s0040-4039(00)83873-3

  日期：1986.1

  Dialkyl-nitroxide radicals formed from nitric oxide, which trapped two alkyl radicals in consecutive steps, have been detected by Electron Spin Resonance spectroscopy. The structure of radicals was found independent of the way of alkyl radical generation. Stereoselectivity of radical trapping was observed for secondary alkyl radicals with chiral carbons.

  由一氧化氮形成的二烷基硝基氧自由基在连续的步骤中捕获了两个烷基自由基，已通过电子自旋共振光谱法进行了检测。发现自由基的结构与烷基自由基的产生方式无关。对于具有手性碳的仲烷基，观察到了自由基捕获的立体选择性。