| 190247-58-6

• CAS: 190247-58-6
• 化学式: CH₄O*C₁₃H₁₁ClInN₅O₂S₂
• 分子量: 515.71
• InChiKey: DJBGCAVTUWKIPD-UPPKIKIDSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 disodium maleonitriledithiolato 以 甲醇 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Mixed-ligand complexes of indium(III). Reactions of [InCl3(L1)(MeOH)] with bidentate ligands. Synthesis, characterization and X-ray structures of [In(L1)Cl(ox)(OH2)]·2H2O, [In(L1)Cl(mnt)]·MeOH and [In(pythio)3] [L1 = pyridine-2,6-bis(acetyloxime), ox2− = oxalate, mnt2− = 1,2-dicyanoethene-1,2-dithiolate, pythio− = pyridine-2-thiolate]

  摘要：

  [InCl3(L-1)(MeOH)] [L-1 = pyridine-2,6-bis(acetyloxime), 2,6-C5H3N(C2H3NOH)(2)] reacts with bidentate ligands by ligand exchange. A seven-coordinate complex of the composition [In(L-1)Cl(ox)(OH2)] is formed with potassium oxalate (K(2)ox). The oxalato ligand occupies the equatorial plane of a pentagonal bipyramid together with the tridentate amine oxime. With sodium 1,2-dicyanoethene-1,2-dithiolate (Na(2)mnt) the analogous reaction produces a six-coordinate mixed ligand complex, [In(L-1)Cl(mnt)], which has a distorted octahedral coordination sphere. Ligands which form four-membered chelate rings like dialkyldithiocarbamates, R(2)dtc(-), or pyridine-2-thiolate, pythio(-), are able to replace all ligands of [InCl3(L-1)(MeOH)] to form neutral tris chelates. The structure of [In(pythio)(3)] has been elucidated showing a strong distortion of the coordination polyhedron from the idealized octahedral geometry. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00536-0