rhodium(I)(COD)[(R,R)-N,N'-bis(tert-butanesulfinyl)acetamidinate] | 369384-83-8

• 英文名称: rhodium(I)(COD)[(R,R)-N,N'-bis(tert-butanesulfinyl)acetamidinate]
• CAS: 369384-83-8
• 化学式: C₁₈H₃₃N₂O₂RhS₂
• 分子量: 476.51
• InChiKey: YXESOGSPIJYJSO-FEDRJSOTSA-N

反应信息

• 作为产物：
  描述：

  chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 (R,R)-N,N'-bis(tert-butanesulfinyl)acetamidine 在 tert-BuOK 作用下， 以 甲苯 为溶剂， 以73%的产率得到rhodium(I)(COD)[(R,R)-N,N'-bis(tert-butanesulfinyl)acetamidinate]
  参考文献：
  名称：

  Synthesis and Crystal Structure of a Unique and Homochiral N,S-Bonded N,N‘-Bis(tert-butanesulfinyl)amidinate Rhodium(I) Complex

  摘要：

  A novel N,N ' -bis(sulfinyl)amidine ligand has been synthesized from optically pure (R)-tert-butanesulfinamide. Deprotonation of this ligand and stirring with (Rh(COD)Cl-2) afford a structurally unique homochiral N,S-bonded metallocycle with rhodium(I). This is the first reported example of a complex involving a bis(sulfinyl)amidinate ligand and any transition metal center.

  DOI：

  10.1021/ic0104205