tetraisobutylamine complex of 2,8,14,20-tetraheptylpentacyclo[19.3.1.1(3,7).1(9,13),1(15,19)]octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaen-6,10,12,16,18,22,24,4-tetraisobutylborate | 1384269-29-7

• 英文名称: tetraisobutylamine complex of 2,8,14,20-tetraheptylpentacyclo[19.3.1.1(3,7).1(9,13),1(15,19)]octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaen-6,10,12,16,18,22,24,4-tetraisobutylborate
• CAS: 1384269-29-7
• 化学式: C₈₈H₁₅₂B₄N₄O₁₂
• 分子量: 1501.44
• InChiKey: YKGYLSAOVXTFDO-UNIDEBNKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,8,14,20-tetraheptylpentacyclo[19.3.1.1(3,7).1(9.13).1(15,19)]octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaen-6,10,12,16,18,22,24,4-tetraisobutyl borate 、 异丁胺 以 苯 为溶剂， 以80%的产率得到tetraisobutylamine complex of 2,8,14,20-tetraheptylpentacyclo[19.3.1.1(3,7).1(9,13),1(15,19)]octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaen-6,10,12,16,18,22,24,4-tetraisobutylborate
  参考文献：
  名称：

  Borylation of calix[4]resorcinols under ultrasonic irradiation

  摘要：

  The use of ultrasonic irradiation in the reactions of trialkyl borates with octahydroxytetraoctyl[l (4)] metacyclophane allowed us obtaining tetraalkoxyboratocavitands with higher yields and under milder conditions. We first obtained 1,3,2-dioxaborolane and 1,3,2-dioxaborinane derivatives of tetraoctyl[l (4)]metacyclophane using ultrasonic irradiation. Boratocavitands were converted into the corresponding amine complexes with isobutylamine.

  DOI：

  10.1134/s107036321205009x