[(2-[(CH3)2NCH2]C6H4-)nBuSnF2](n) | 1061582-83-9

• 英文名称: [(2-[(CH3)2NCH2]C6H4-)nBuSnF2](n)
• CAS: 1061582-83-9
• 化学式: C₁₃H₂₁F₂NSn
• 分子量: 348.023
• InChiKey: VRNJFSNKPPFLNM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氟化铵 、 (2-(N,N-dimethylaminomethyl)phenyl)(n-Bu)SnCl₂ 以 甲醇 为溶剂， 生成 [(2-[(CH3)2NCH2]C6H4-)nBuSnF2](n)
  参考文献：
  名称：

  The differences in solid state structures of C,N-chelated nbutyltin(IV) fluorides

  摘要：

  The solid state structures of products of. uorination of LCNnBuSnCl2 ( where LCN is 2-[( CH3) 2NCH2] C6H4 -) by different methods are reported. The reaction of 3 equiv. of [ NH4]+[ LCNnBuSnF3] and Pr( OTf) 3 led to dimeric arrangement [ LCNnBuSnF( l- F) 2SnLCNnBuF] 2HOTf. Two different polymorphs of polymeric [ LCNnBuSnF2] n have been obtained by crystallization. Prepared compounds were studied by X- ray crystallographic methods, DSC and theoretical calculations at the B3LYP/ LANL2DZ level. (c) 2008 Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2008.06.010