[(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2CH2N=NN=NCH2CH2Ph)] | 1309604-27-0

• 英文名称: [(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2CH2N=NN=NCH2CH2Ph)]
• CAS: 1309604-27-0
• 化学式: C₃₅H₅₁ClN₄ORu
• 分子量: 680.339
• InChiKey: ULTZFRCESASEHC-PRDGZKQISA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [RuCl2(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)]2 、 (2-叠氮基乙基)-苯 以 四氢呋喃 为溶剂， 以72%的产率得到[(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)RuCl(PhCH2CH2N=NN=NCH2CH2Ph)]
  参考文献：
  名称：

  Beyond Click-Chemistry: Transformation of Azides with Cyclopentadienyl Ruthenium Complexes

  摘要：

  The cyclopentadienyl Ru complexes Cp*RuCl-(cod) (cod = 1,5-cyclooctadiene), Cp*RuCl(PPh3)(2), and [Cp boolean AND RuCl2](2) (Cp boolean AND = eta(5)-1-methoxy-2,4-di-tert-butyl-3-neo-pentylcyclopentadienyl) are able to catalyze the decomposition of benzyl azides to give 1,3,5-triphenyl-2,4-diazapenta-1,4-diene ("hydrobenzamide"), benzyl-benzylideneamine, and benzonitrile. Reactions with the catalyst precursor [Cp boolean AND RuCl2](2) are particularly fast and give hydrobenzamide with high selectivity. A similar coupling reaction is observed for other benzylic azides but not for (2-azidoethyl)benzene and ethyl-4-azidobutanoate. If the reactions are performed in the presence of water, benzylic azides are converted into aldehydes. Mononuclear tetrazene complexes are formed in stoichiometric reactions of [Cp boolean AND RuCl2](2) with benzyl azide and (2-azidoethyl)benzene.

  DOI：

  10.1021/om200295c