| 1071288-04-4

• CAS: 1071288-04-4
• 化学式: C₁₈H₁₉MnO₂P
• 分子量: 353.259
• InChiKey: WEHHQHGRTCXNJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 ammonium chloride 以 not given 为溶剂， 生成 [Mn(cyclopentadienyl)(CO)2(η1-Z-P(Mes)CHMe)]
  参考文献：
  名称：

  Generation of α-Phosphinocarbene Complexes and Their Evolution: New Light on Relevant Isomerization Pathways

  摘要：

  The eta(1)-alpha-phosphinocarbene complex CP(CO)(2)Mn=CR(PHMes) (R = Ph, Me) is generated by nucleophilic attack of MesPH(2) at the electrophilic center of the cationic Mn-carbyne complex [Cp(CO)(2)Mn CR](+), followed by deprotonation. One of its identified isomerization pathways to eta(1)-phosphaalkene derivatives is shown to be both base-catalyzed and stereoselective, and to involve a transient phosphidocarbene species engaged in an acid-catalyzed migratory CO-insertion step.

  DOI：

  10.1021/om800884v
• 作为产物：
  描述：

  在 n-BuLi 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Generation of α-Phosphinocarbene Complexes and Their Evolution: New Light on Relevant Isomerization Pathways

  摘要：

  The eta(1)-alpha-phosphinocarbene complex CP(CO)(2)Mn=CR(PHMes) (R = Ph, Me) is generated by nucleophilic attack of MesPH(2) at the electrophilic center of the cationic Mn-carbyne complex [Cp(CO)(2)Mn CR](+), followed by deprotonation. One of its identified isomerization pathways to eta(1)-phosphaalkene derivatives is shown to be both base-catalyzed and stereoselective, and to involve a transient phosphidocarbene species engaged in an acid-catalyzed migratory CO-insertion step.

  DOI：

  10.1021/om800884v