Ru(η⁶-C₆H₆)Br₂(PPh₃) | 39732-37-1

• 英文名称: Ru(η⁶-C₆H₆)Br₂(PPh₃)
• CAS: 39732-37-1
• 化学式: C₂₄H₂₁Br₂PRu
• 分子量: 601.283
• InChiKey: DFHKOBYUCNTRIY-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  、 乙基溴苯 以 丁酮 为溶剂， 反应 3.0h， 生成 Ru(η⁶-C₆H₆)Br₂(PPh₃)
  参考文献：
  名称：

  Synthesis and comparative behavior of ruthena(II)cycles bearing benzene ligand in the radical polymerization of styrene and vinyl acetate

  摘要：

  A series of half-sandwich ruthenium(II) complexes of the type [Ru(eta(6)-C6H6)(NnC)LIPF6 (L = PPh3, P(nBu)(3), SbPh3, MeCN), bearing cyclometalated N,N-dimethylbenzylamine (la d) and 2-phenylpyridine (2a -d) moieties, has been efficiently prepared by ligand substitution. The molecular structures of the new compounds were unequivocally determined by single-crystal X-ray diffraction. The catalytic activity of the complexes in the radical polymerizations of styrene and vinyl acetate was evaluated, and a comparative structure activity analysis was performed. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2015.10.013