[Ti2Ca4(μ6-O)Cl4(2-methoxyethylate)10] | 1054560-20-1

• 英文名称: [Ti2Ca4(μ6-O)Cl4(2-methoxyethylate)10]
• CAS: 1054560-20-1；1169860-74-5
• 化学式: C₃₀H₇₀Ca₄Cl₄O₂₁Ti₂
• 分子量: 1164.76
• InChiKey: LJUDEEOPZJQWEI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯二茂钛 、 di(2-methoxyethoxy)-calcium 以 乙二醇甲醚 为溶剂， 生成 [Ti2Ca4(μ6-O)Cl4(2-methoxyethylate)10]
  参考文献：
  名称：

  Unexpected Cyclopentadienyl/Alkoxo Ligand Exchange in Titano- and Zirconocene. New Opportunities

  摘要：

  A simple new route to access heterometallic alkoxo precursors for a wide range of materials is repoiled. This unique synthetic method comprises elimination of the cyclopentadienyl ring from CP2MCl2 (M = Ti, Zr) as CpH in the presence of M'(OR)(2) (M' = Ca, Mn; OR = OCH2CH2OCH3 or OEt) in an alcohol as a source of protons. In one-pot reactions, we have prepared four different compounds with Ti2Ca4(mu(6)-O), CP2Zr2Ca4(mu(4)-Cl), ZrjoMn(10)(mu(3)-O)(14), and CP3Ti2(mu-OEt)(2) motifs. The compounds were characterized by single-crystal X-ray structural analysis and NMR spectroscopy.

  DOI：

  10.1021/ic8009749