di-μ-oxodi-μ-acetatobis(pentamethylcyclopentadienyl)dimolybdenum(IV) | 615560-71-9

• 英文名称: di-μ-oxodi-μ-acetatobis(pentamethylcyclopentadienyl)dimolybdenum(IV)
• CAS: 615560-71-9
• 化学式: C₂₄H₃₆Mo₂O₆
• 分子量: 612.426
• InChiKey: POIIFVCFOSHLLR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(pentamethylcyclopentadienyl)2Mo2O5] 、 溶剂黄146 在 Zn 作用下， 以 甲醇 、 水 、 溶剂黄146 为溶剂， 以14.7%的产率得到di-μ-oxodi-μ-acetatobis(pentamethylcyclopentadienyl)dimolybdenum(IV)
  参考文献：
  名称：

  High oxidation state aqueous organometallics: synthesis and structure of a dinuclear oxo(pentamethylcyclopentadienyl)acetato complex of molybdenum(IV), [Cp*Mo(μ-O)(μ-O2CCH3)]2

  摘要：

  The zinc reduction of (Cp2Mo2O5)-Mo-* in a MeOH-H2O mixture in the presence of acetic acid affords the diamagnetic dinuclear compound [Cp*MoO(O2CCH3)](2). An X-ray structural investigation reveals a novel dioxo- and diacetato-bridged structure, with a relatively strong metal-metal bond [2.5524(3) Angstrom]. The compound exhibits a reversible one-electron oxidation process in the cyclic voltammogram. A comparison with other related structures reveals the effect of the electric charge on the mononuclear or dinuclear structural choice. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01439-1