[RuCl2(η6-C6Me6)(P(OEt)3)] | 869384-26-9

• 英文名称: [RuCl2(η6-C6Me6)(P(OEt)3)]
• CAS: 869384-26-9
• 化学式: C₁₈H₃₃Cl₂O₃PRu
• 分子量: 500.408
• InChiKey: SDGKNOQQIBRAJW-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  tetraphenylphosphonium trithiomolybdate 、 [RuCl2(η6-C6Me6)(P(OEt)3)] 以 甲醇 为溶剂， 以89%的产率得到[RuCl2(η6-C6Me6)(P(OEt)3)MoOS(μ2-S)2]
  参考文献：
  名称：

  Synthesis and Crystal Structure of an Open Capsule-Type Octanuclear Heterometallic Sulfide Cluster with a Linked Incomplete Double Cubane Framework without an Intramolecular Inversion Center

  摘要：

  An open capsule-type octanuclear heterometallic sulfide cluster without an intramolecular inversion center [Ru(eta(6)-C6Me6){P(OMe)(3)}{MoO(mu(3)-S)(3)}(Cul)(2)}(2) (5) has been synthesized for the first time by stepwise connection of three mononuclear building blocks, i.e., (i) [RuCl2(eta(6)-C6Me6){P(OMe)(3)}] (1a) as an octahedral terminal building block to control the direction of cluster expansion, (ii) [MoOS3](2-) as a tetrahedral polydentate building block owing to the strong coordination ability of the S atoms, and (iii) a Cul building block to form a trigonal planar (mu-S)(2)Cul unit or to form a linkage unit of two incomplete cubane-type octanuclear frameworks. The stepwise connection was made in the following order: [RuCl2(eta(6)-C6Me6){P(OMe)(3)}] (1a, mononuclear) -> [Ru(eta(6)-C6Me6){P(OMe)(3)}{MoOS(mu(2)-S)(2)}] (2a, dinuclear) -> [Ru(eta(6)-C6Me6){P(OMe)(3)}{MoO(mu(2)-S)(2)(mu(3)-S)}Cul] (3a, butterfly-type trinuclear) -> [Ru(eta(6)-C6Me6){P(OMe)(3)}{MoO(mu(3)-S)(3)}(Cul)(2)](2) (5). When P(OMe)(3) was replaced by P(OEt)(3), which is more bulky than P(OMe)(3), in the starting ruthenium building block [RuCl2(eta(6)-C6Me6){P(OEt)(3))] (1b, mononuclear), only the tetranuclear incomplete single cubane cluster [Ru(eta(6)-C6Me6){P(OEt)(3)}{MoO(mu(3)-S)(3)}(Cul)(2)] (6) was generated, owing to the steric effect of P(OEt)(3).

  DOI：

  10.1021/ja051748q
• 作为产物：
  描述：

  [RuCl2(hexamethylbenzene)]2 、 亚磷酸三乙酯 以 乙醚 为溶剂， 以96%的产率得到[RuCl2(η6-C6Me6)(P(OEt)3)]
  参考文献：
  名称：

  Synthesis and Crystal Structure of an Open Capsule-Type Octanuclear Heterometallic Sulfide Cluster with a Linked Incomplete Double Cubane Framework without an Intramolecular Inversion Center

  摘要：

  An open capsule-type octanuclear heterometallic sulfide cluster without an intramolecular inversion center [Ru(eta(6)-C6Me6){P(OMe)(3)}{MoO(mu(3)-S)(3)}(Cul)(2)}(2) (5) has been synthesized for the first time by stepwise connection of three mononuclear building blocks, i.e., (i) [RuCl2(eta(6)-C6Me6){P(OMe)(3)}] (1a) as an octahedral terminal building block to control the direction of cluster expansion, (ii) [MoOS3](2-) as a tetrahedral polydentate building block owing to the strong coordination ability of the S atoms, and (iii) a Cul building block to form a trigonal planar (mu-S)(2)Cul unit or to form a linkage unit of two incomplete cubane-type octanuclear frameworks. The stepwise connection was made in the following order: [RuCl2(eta(6)-C6Me6){P(OMe)(3)}] (1a, mononuclear) -> [Ru(eta(6)-C6Me6){P(OMe)(3)}{MoOS(mu(2)-S)(2)}] (2a, dinuclear) -> [Ru(eta(6)-C6Me6){P(OMe)(3)}{MoO(mu(2)-S)(2)(mu(3)-S)}Cul] (3a, butterfly-type trinuclear) -> [Ru(eta(6)-C6Me6){P(OMe)(3)}{MoO(mu(3)-S)(3)}(Cul)(2)](2) (5). When P(OMe)(3) was replaced by P(OEt)(3), which is more bulky than P(OMe)(3), in the starting ruthenium building block [RuCl2(eta(6)-C6Me6){P(OEt)(3))] (1b, mononuclear), only the tetranuclear incomplete single cubane cluster [Ru(eta(6)-C6Me6){P(OEt)(3)}{MoO(mu(3)-S)(3)}(Cul)(2)] (6) was generated, owing to the steric effect of P(OEt)(3).

  DOI：

  10.1021/ja051748q