Cu(N,N'-ethylenedi(3-methoxysalicylideneimine))Ba(tetramethylheptanedionate)2 | 954110-96-4

• 英文名称: Cu(N,N'-ethylenedi(3-methoxysalicylideneimine))Ba(tetramethylheptanedionate)2
• 英文别名: [Cu(L(1))Ba(thd)2]
• CAS: 954110-96-4
• 化学式: C₄₀H₅₆BaCuN₂O₈
• 分子量: 893.769
• InChiKey: BJOLWBHXMPCGMP-WCLOSASOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2,6,6-四甲基-3,5-庚二酮 、 barium hydroxide octahydrate 、 monoaqua 3-methoxysalicylaldehyde-ethyldiamine copper(II) 以 甲醇 为溶剂， 以56%的产率得到Cu(N,N'-ethylenedi(3-methoxysalicylideneimine))Ba(tetramethylheptanedionate)2
  参考文献：
  名称：

  Varying the metal/metal ratio in related Cu–Ca complexes

  摘要：

  We demonstrate with the help of structural determinations and spectroscopic data that the nuclearity of Cu-Ca complexes derived from compartmental Schiff base ligands does not depend on the ionic radius of calcium. The main factors governing these reactions are the different affinities of the calcium ions for the anionic species present in solution: the tetradentate O2O2 coordination site of the ligand and the nitrato ions. Because these affinities do vary upon going from calcium to lanthanide ions, it is not possible to use the template effect of the trinuclear Cu-Ca-Cu complexes in order to prepare the corresponding Cu-Ln-Cu complexes. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.05.019