[{RuCl(CO)(triphenylphosphine)}2(μ-Cl)(μ-η²(S),η²(S')-N(iPr2PS)2)] | 1401318-45-3

• 英文名称: [{RuCl(CO)(triphenylphosphine)}2(μ-Cl)(μ-η²(S),η²(S')-N(iPr2PS)2)]
• CAS: 1401318-45-3
• 化学式: C₅₀H₅₈Cl₃NO₂P₄Ru₂S₂
• 分子量: 1201.54
• InChiKey: HWMYUTJYXWMENQ-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  K[iPr2P(S)NP(S)iPr2] 、 tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II) 以 四氢呋喃 为溶剂， 以70%的产率得到[{RuCl(CO)(triphenylphosphine)}2(μ-Cl)(μ-η²(S),η²(S')-N(iPr2PS)2)]
  参考文献：
  名称：

  Mutual transformation between mono- and binuclear ruthenium complexes and their reactions with iminobis(diisopropylphosphinesulfide) ligand

  摘要：

  Treatment of RuCl3 center dot xH(2)O, PPh3 and HCHO in boiling 2-methoxyethanol led to isolation of complex [(PPh3)(CO)ClRu(mu-Cl)(3)Ru(CO)(PPh3)(2)] (1) and [RuCl2(CO)(CH3OH)(PPh3)(2)](2), which could convert to each other under special conditions. 1 could turn to 2 in MeOH/Et2O solvent in the presence of excess PPh3, while 2 could transform to 1 in CH2Cl2/n-hexane solvent. Reactions of complex 1 or 2 with KN[(Pr2P)-Pr-i(S)](2) afforded complex [{RuCl(CO)(PPh3)}(2)(mu-Cl)(mu-eta(2)(S),eta(2)(S')-N((Pr2PS)-Pr-i)(2))] (3), in which the N[P(S)Pr-i(2)](2) ligand acts as a dinucleating tetraconnective unit through both sulfur atoms between two Ru(II) atoms. Complexes 1, 2, and 3 have been characterized spectroscopically and by X-ray crystallography. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.05.036