tetrakis(cyclohexylpyrazino)porphyrazinatomagnesium(II) | 1223471-87-1

• 英文名称: tetrakis(cyclohexylpyrazino)porphyrazinatomagnesium(II)
• CAS: 1223471-87-1
• 化学式: C₄₀H₃₂MgN₁₆
• 分子量: 761.106
• InChiKey: PTTXIBCHAWKSBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,3-cyano-5,6,7,8-tetrahydroquinoxaline 在 magnesium n-propoxide 作用下， 以 丙醇 为溶剂， 反应 6.0h， 以60%的产率得到tetrakis(cyclohexylpyrazino)porphyrazinatomagnesium(II)
  参考文献：
  名称：

  The symmetrical porphyrazine with annulated six membered rings

  摘要：

  Tetrakis(cyclohexylpyrazino)porphyrazinato magnesium(II) with annulated six membered rings has been prepared by two different methods. In Method A: cyclotetramerization of 2,3-dicyano-5,6-cyclohexanopyrazine (1) in the presence of Mg(OPr)(2) in n-propanol afforded the tetrakis(cyclohexylpyrazino)porphyrazinato magnesium(II) (2). In Method B: selenodiazole rings on the periphery of tetrakis(selenodiazole)porphyrazinato magnesium(II) were opened by the action of H2S to yield the vicinal diamino functionalities. The ring closure of the vicinal diamino groups with 1,2-cyclohexanedione afforded the tetrakis(cyclohexylpyrazino) porphyrazinato magnesium(II) (2). (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.12.012