[Nd(salpn)(THF)Cl(LiCl(C4H8O))2]2 | 934165-88-5

• 英文名称: [Nd(salpn)(THF)Cl(LiCl(C4H8O))2]2
• CAS: 934165-88-5
• 化学式: C₅₈H₈₀Cl₆Li₄N₄Nd₂O₁₀
• 分子量: 1522.26
• InChiKey: UUFSSTGAVBBUPB-JQFNJWKXSA-D

反应信息

• 作为产物：
  描述：

  、 [Na2(salpn)(THF)] 在 NaOH 作用下， 以 四氢呋喃 为溶剂， 以72%的产率得到[Nd(salpn)(THF)Cl(LiCl(C4H8O))2]2
  参考文献：
  名称：

  Cubism

  摘要：

  The syntheses of [Li-2(salen)(DME)](2), [Li-2(salpn)(THF)](2), [Na-2(salpn)(Et2O)](2) and [Na-2(salpn)(DME)](2) (H(2)salen = (o-HOC6H4CH= NCH2)(2); H(2)salpn = (o-HOC6H4CH=NCH2)(2)CH2) involve treatment of the appropriate Schiff base with either n-BuLi or MN(SiMe3)(2) (M = Li, Na) in DME, THF or Et2O. The X-ray crystal structures of these compounds show that they all have very similar structural motifs comprising M4O4 (M = Li or Na) 'cubanoid' cores. The X-ray crystal structure of [{Nd(salpn)(THF)Cl}{LiCl(THF)}(2)](2) obtained by treatment of [Na-2(salpn)(THF)] with [NdCl3 center dot 2(LiCl)] has a dimeric [Nd(salpn)(THF)Cl](2) molecule sandwiched between two Li2Cl2(THF)(2) units. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.03.012