[(η(5)-C5Me5)TiF(μ-F)(μ-OCO-o-C6H4COOSiMe3)]2 | 205492-26-8

• 英文名称: [(η(5)-C5Me5)TiF(μ-F)(μ-OCO-o-C6H4COOSiMe3)]2
• CAS: 205492-26-8
• 化学式: C₄₂H₅₆F₄O₈Si₂Ti₂
• 分子量: 916.826
• InChiKey: DRHXYPIIFXBIKT-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (pentamethylcyclopentadienyl)titanium fluoride 、 ortho-phthalic acid bis(trimethylsilyl) ester 以 甲苯 为溶剂， 以73%的产率得到[(η(5)-C5Me5)TiF(μ-F)(μ-OCO-o-C6H4COOSiMe3)]2
  参考文献：
  名称：

  Synthesis and structural characterization of sulfonates, phosphinates and carboxylates of organometallic Group 4 metal fluorides1Dedicated to Professor Ken Wade on the occasion of his 65th birthday and in recognition of his outstanding contributions to inorganic and organometallic chemistry.1

  摘要：

  Reaction of [Cp* TiF3] (Cp* = (eta(5)-C5Me5)) with Me3SiOSO2-p-C6H4CH3, Me3SiOPOPh2 and 1,2-(Me3SiOCO)(2)C6H4 yields the dinuclear complexes [{Cp* TiF(mu-F)(mu-OSO2-p-C6H4CH3)}(2)] (1), [{Cp*TiF(mu-F)(mu-OPOPh2)}(2)] (2) and [{Cp* TiF(mu-F)(mu-OCO-o-C6H4CO2SiMe3)}(2)] (3). The molecular structures of 1 and 2 have been determined by single-crystal X-ray analysis. In complexes 1-3, the two titanium atoms are connected by bridging fluorine atoms as well as bridging sulfonate, phosphinate and carboxylate groups respectively. Each titanium atom is also bonded to a terminal fluorine atom. Reaction of [Cp-2* ZrF2] with 1,2-(Me3SiOCO)(2)C6H4 leads to the mononuclear pentacoordinate 18-electron species [Cp-2*ZrF(mu-OCO-o-C6H4CO2SiMe3)] (4) and its structure was determined by X-ray crystallographic methods. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(96)06818-0