trans-[Co2(CO)6(3,5-(CF3)2C6H3P(i-Pr)2)2] | 850700-56-0

• 英文名称: trans-[Co2(CO)6(3,5-(CF3)2C6H3P(i-Pr)2)2]
• CAS: 850700-56-0
• 化学式: C₃₄H₃₄Co₂F₁₂O₆P₂
• 分子量: 946.555
• InChiKey: VHLIZRHOCVWTCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 P(i)Pr2[3,5-(CF3)2C6H3] 以 苯 为溶剂， 以68%的产率得到trans-[Co2(CO)6(3,5-(CF3)2C6H3P(i-Pr)2)2]
  参考文献：
  名称：

  Solubility of trans-Co2(CO)6 [3,5-bis(CF3)C6H3P(i-C3H7)2] in dense carbon dioxide

  摘要：

  The title compound (1) was prepared by the reaction of 3,5-bis(CF3)C6H3P(i-C3H7)(2) (L1) and Co-2(CO)(8). Its solubility in super-critical carbon dioxide was measured at varying temperatures and pressures using a modified analytical extraction device. Solubility data were determined in the temperature and pressure ranges between 40 and 70 degrees C and between 100 and 300 bar, respectively. The solubility of 1 is lower compared to (p-CF3C6H4)(3)P, but much higher than for transition metal complexes bearing phosphines without fluorinated substituents. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.11.053