α,α'-μ-o-xylyl-bis(pentamethylyclopentadienyltricarbonylmolybdenum) | 200271-68-7

• 英文名称: α,α'-μ-o-xylyl-bis(pentamethylyclopentadienyltricarbonylmolybdenum)
• CAS: 200271-68-7
• 化学式: C₃₄H₃₈Mo₂O₆
• 分子量: 734.552
• InChiKey: PIORNZUTLFWWAY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  邻二氯苄 、 sodium pentamethylcyclopentadienide 、 molybdenum hexacarbonyl 以 四氢呋喃 为溶剂， 以46%的产率得到α,α'-μ-o-xylyl-bis(pentamethylyclopentadienyltricarbonylmolybdenum)
  参考文献：
  名称：

  Synthesis and characterization of dinuclear p-, m- and o-xylyl bridged complexes of molybdenum and tungsten. The crystal structures of μ-p-xylyl- bis(η5-pentamethyl-cyclopentadienyltri- carbonylmolybdenum) and μ-m-xylyl-bis(η5- pentamethylcyclopentadienyltricarbonyltungsten)

  摘要：

  The reactions of eta(5)-Cp*M(CO)(3)Na(M = Mo, W) with alpha,alpha '-p-, m- and o-dichloro-xylenes yielded p-, m- and o-xylyl bridged dinuclear complexes of eta(5)-Cp*M(CO)(3) in high yields. All of such new complexes are stable to air and water, even stable in dilute acids and bases. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00198-8