| 183280-86-6

• CAS: 183280-86-6
• 化学式: C₃₂H₄₄Al₂N₂O₂
• 分子量: 542.677
• InChiKey: BEULTBYZVQICQX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 甲苯 为溶剂， 以43%的产率得到
  参考文献：
  名称：

  Use of the Salan Ligands To Form Bimetallic Aluminum Complexes

  摘要：

  The syntheses and characterization of two types of complexes having a metal-Salan ligand stoichiometry of 2:1 (where Salan = N,N'-bis(o-hydroxybenzyl)-1,2-diaminoethane (SaleanH(4)), N,N'-bis(o-hydroxybenzyl)-1,2-diaminobenzene (SalophanH(4)), and N,N'-bis(o-hydroxybenzyl)-1,2-diamino-(4,5-dimethyl)benzene (SalomphanH(4))) are reported. The first are designated type I and are of the general formula LHAlR(AlR(2)), where L = Salean [R = Me (1), Et (2), (i)Bu (3)], Salophan [R = Me (4), Et (5), (i)Bu (6)], and Salomphan [R = Me (7), Et (8), (i)Bu (9)]. Formed by the thermolysis of RH from the type I complexes, the type II complexes are of the general formula [LAl(AlR(2))](2), where L = Salophan [R = Me (10), (i)Bu (11)] and Salomphan [R = Me (12), (i)Bu(13)]. The type I complexes can be converted into the trimetallic derivatives SalanAlR(AlR(2))(2) (type III) through the addition of AlR(3) while the type II cannot. One structurally characterized trimetallic complex, SalophanAlEt(AlEt(2))(2) (14), serves as a representative of this successful transformation.

  DOI：

  10.1021/om960505r
• 作为产物：
  描述：

  三异丁基铝 、 2-[[2-[(2-羟基苯基)甲氨基]苯胺基]甲基]苯酚 以 甲苯 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Use of the Salan Ligands To Form Bimetallic Aluminum Complexes

  摘要：

  The syntheses and characterization of two types of complexes having a metal-Salan ligand stoichiometry of 2:1 (where Salan = N,N'-bis(o-hydroxybenzyl)-1,2-diaminoethane (SaleanH(4)), N,N'-bis(o-hydroxybenzyl)-1,2-diaminobenzene (SalophanH(4)), and N,N'-bis(o-hydroxybenzyl)-1,2-diamino-(4,5-dimethyl)benzene (SalomphanH(4))) are reported. The first are designated type I and are of the general formula LHAlR(AlR(2)), where L = Salean [R = Me (1), Et (2), (i)Bu (3)], Salophan [R = Me (4), Et (5), (i)Bu (6)], and Salomphan [R = Me (7), Et (8), (i)Bu (9)]. Formed by the thermolysis of RH from the type I complexes, the type II complexes are of the general formula [LAl(AlR(2))](2), where L = Salophan [R = Me (10), (i)Bu (11)] and Salomphan [R = Me (12), (i)Bu(13)]. The type I complexes can be converted into the trimetallic derivatives SalanAlR(AlR(2))(2) (type III) through the addition of AlR(3) while the type II cannot. One structurally characterized trimetallic complex, SalophanAlEt(AlEt(2))(2) (14), serves as a representative of this successful transformation.

  DOI：

  10.1021/om960505r