[(η6-cymene)Ru(2,3-bis(α-pyridyl)quinoxaline)Cl]PF6 | 671191-40-5

• 英文名称: [(η6-cymene)Ru(2,3-bis(α-pyridyl)quinoxaline)Cl]PF6
• CAS: 671191-40-5
• 化学式: C₂₈H₂₆ClN₄Ru*F₆P
• 分子量: 700.028
• InChiKey: XIBSQOQZPOFCGN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 2,3-二吡啶-2-基喹喔啉 以 甲醇 为溶剂， 以66.6%的产率得到[(η6-cymene)Ru(2,3-bis(α-pyridyl)quinoxaline)Cl]PF6
  参考文献：
  名称：

  Reactivity studies of η6-arene ruthenium (II) dimers with polypyridyl ligands: isolation of mono, binuclear p-cymene ruthenium (II) complexes and bisterpyridine ruthenium (II) complexes

  摘要：

  The complexes [(eta(6)-p-cymene)RuCl(L-2)](+) where L-2 = 2,2'-biquinoline (biqui) (3), 2,9-dimethyl 4,7-diphenyl-1,10-phenanthroline (ddp) (4), and 2,3-bis(alpha-pyridyl) quinoxaline (bpq) (5) were obtained by halide bridge cleavage of [{(eta(6)-p-cymene)Ru(mu-Cl)}(2)Cl-2] (1) with the corresponding ligands. The ligand bridged binuclear compound [{(eta(6)-cymene)RuCl}(2)(bpq)](2+) (6) was also obtained by treating I with stoichiometric amount of bpq in methanol. The reactions of [{(eta(6)-arene)Ru(mu-Cl)}(2)Cl-2], {arene=p-cymene (1), hexamethylbenzene (2)1 with substituted phenylterpyridines (x-phterpy, x = H, CH3, OCH3) yielded his terpyridine complexes of the type [(x-phterpy)(2)Ru](2+) by the facile displacement of eta(6)-arene ring as well as chloride ligands. These complexes were characterized by FT-NMR, FT-IR spectroscopy, and analytical data. The molecular structures of [(eta(6)-p-cymene)RuCl(biqui)]PF6 (3) and [(eta(6)-p-cymene)RuCl(bpq)]PF6 (5) have been determined by single crystal X-ray diffraction study. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00460-1