(η(5)-C5Me5)(η(3)-N-methoxycarbonyl-6-methoxycarbonyl-5-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl | 191919-96-7

• 英文名称: (η(5)-C5Me5)(η(3)-N-methoxycarbonyl-6-methoxycarbonyl-5-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl
• CAS: 191919-96-7
• 化学式: C₂₈H₃₄ClNO₆RuS
• 分子量: 649.17
• InChiKey: WXUDAIONMATZEB-DUHMYJLJSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloro(1,5-cyclooctadiene)(pentamethylcyclopentadiene)ruthenium(II) 、 3-Methyl-6-(toluene-4-sulfonyl)-7-aza-bicyclo[2.2.1]hepta-2,5-diene-2,7-dicarboxylic acid dimethyl ester 以 四氢呋喃 为溶剂， 以75%的产率得到(η(5)-C5Me5)(η(3)-N-methoxycarbonyl-6-methoxycarbonyl-5-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl
  参考文献：
  名称：

  Regioselective synthesis of η3-(N-methoxycarbonyl-7-azabicyclo[2.2.1]he ta-2,5-dienyl)-η5-(C5Me5)RuCl complexes

  摘要：

  The reactions of Cp*Ru(COD)Cl and CpRu(COD)Cl with N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-diene derivatives were found to give eta(3)-[N(CO2Me)C6H3(2-p-MeC6H4SO2)(6-CO2Me)(5-Me)]CpRuCl and eta(3)-[N(CO2Me)-7-azabicyclo[2.2.1]heptadienyl]Cp*RuCl complexes in good yields (54-78%). The coordination reaction was found to take place regioselectively at the least substituted pi-bond of the N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-diene derivatives. The structures of the complexes were determined by H-1 and C-13 NMR and the structure of eta(3)-[N(CO2Me)C6H3(2-p-MeC6H4SO2)(6-CO2Me)(5-Me)]Cp*RuCl was unequivocally established by X-ray crystallography.

  DOI：

  10.1016/s0022-328x(96)06827-1