(OC)3Cr(η(6)-C6H5N(CH3)CH2C4H4CH3-η(4))Fe(CO)3 | 203315-30-4

• 英文名称: (OC)3Cr(η(6)-C6H5N(CH3)CH2C4H4CH3-η(4))Fe(CO)3
• CAS: 203315-30-4
• 化学式: C₁₉H₁₇CrFeNO₆
• 分子量: 463.19
• InChiKey: NBSBITXBKHDRCP-ANEYZRQWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三羰基(N-甲基苯胺)铬(0) 、 tricarbonyl(2-6-η-hexadienyl)iron(0) tetrafluoroborate 以 四氢呋喃 为溶剂， 以35%的产率得到(OC)3Cr(η(6)-C6H5N(CH3)CH2C4H4CH3-η(4))Fe(CO)3
  参考文献：
  名称：

  Hydrocarbon bridged metal complexes: XLII. Addition of aniline tricarbonyl chromium complexes to the dienyl ligands of [(η5-H3CC5H5CH3)Fe(CO)3]+ and [(η5-C5H6CH3)Fe(CO)3]+

  摘要：

  Aniline tricarbonyl chromium complexes (eta(6)-C6H4(R)NHR1)Cr(CO)(3) (R = H, CH3; R-1 = H, CH3) were used as nucleophiles for addition to [(eta(5)-H3CC5H5CH3)Fe(CO)(3)](+) and [(eta(5)-C5H6CH3)Fe(CO)(3)](+) to give the heterobimetallic ligand bridged complexes (OC)(3)Cr(eta(6)-C6H4(R)N(R-1)(CH3)C5H5CH3-eta(4))Fe(CO)(3) and (OC)(3)Cr(eta(6)-C6H4(R)N(R-1)C5H6CH3-eta(4))Fe(CO)(3). The structures of (OC)(3)Cr(eta(6)-C6H4(CH3)N(H)(CH3)C5H5CH3-eta(4))Fe(CO)(3) and (OC)(3)Cr(eta(6)-C6H5N(H)C5H6CH3-eta(4))Fe(CO)(3) were determined by X-ray diffraction. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00505-6