[ReO(2,5-diazo-N,N'-dimethylhexyl-1,6-bis(phenylphosphinate))Cl] | 362597-53-3

• 英文名称: [ReO(2,5-diazo-N,N'-dimethylhexyl-1,6-bis(phenylphosphinate))Cl]
• CAS: 362597-53-3
• 化学式: C₁₈H₂₄ClN₂O₅P₂Re
• 分子量: 632.006
• InChiKey: IXNRNZIMEOGBGN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  在 triphenylphosphine 作用下， 以 甲醇 、 氘代乙腈 、 重水 为溶剂， 生成 [ReO(2,5-diazo-N,N'-dimethylhexyl-1,6-bis(phenylphosphinate))Cl] 、 [ReO(2,5-diazo-N,N'-dimethylhexyl-1,6-bis(phenylphosphinate))(SC6H5)]
  参考文献：
  名称：

  [ReO(N₂O₂)X] Complexes:  “4 + 1”?

  摘要：

  [ReO(ppme)X] (where ppme(2-) is 2,5-diazo-N,N ' -dimethylhexyl-1,6-bis(phenylphosphinate), X = Br0.3Cl0.7) has been synthesized via a substitution reaction and structurally characterized. The coordination geometry is a distorted octahedron and one phosphinate coordinates cis and the other trans to the oxo O atom. This coordination mode is conserved in all [ReOppmeX] complexes synthesized in this study. [ReO(ppme)CI] has been prepared by a reduction/complexation reaction from [NH4][ReO4]. [ReO(ppme)Cl] reacts with thiocyanate and benzene thiolate forming [ReO(ppme)X] (X = -NCS, -SC6H5), but the one-pot synthesis of the respective. ternary thiolate complexes from perrhenate was not successful. The reduction/complexation reaction of a thiol, H(2)ppmeCl(4), and perrhenate resulted in the formation of [H(3)ppme][ReO(SR)(4)], the reaction of which with [ReO(ppme)CI] does not lead to [ReO(ppme)SR] in high yields.

  DOI：

  10.1021/ic001416g