trans-[PtCl2(E-HN(OMe)Et)2](18-crown-6) | 1237587-98-2

• 英文名称: trans-[PtCl2(E-HN(OMe)Et)2](18-crown-6)
• CAS: 1237587-98-2
• 化学式: C₈H₁₈Cl₂N₂O₂Pt*C₁₂H₂₄O₆
• 分子量: 704.548
• InChiKey: YQSSCKOKRVXYKK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  18-冠醚-6 、 trans-[PtCl₂(E-HN=C(OMe)Et)2] 以 氯仿 、 丙酮 为溶剂， 生成 trans-[PtCl2(E-HN(OMe)Et)2](18-crown-6)
  参考文献：
  名称：

  18-Crown-6 as a linker for (imino ester)2Pt centers providing their assembly into 1D arrays via hydrogen bonding

  摘要：

  The platinum(II- and IV) complexes trans-[PtCln{HN=C(OMe)Et}(2)] (n=2, 4) were assembled with 18-crown-6 into novel 1D arrays by hydrogen bonding thus forming 1:1 associates. The crystal structure determinations revealed the presence of the N-H center dot center dot center dot O and the non-conventional weak CH center dot center dot center dot O interactions between the imino hydrogen and the methyl hydrogens, respectively, of trans-[PtCln{HN=C(OMe)Et}(2)] and the oxygens of 18-crown-6. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.02.008