tert-butylchloro[3-(dimethylamino)propyl]aluminum | 199918-57-5

• 英文名称: tert-butylchloro[3-(dimethylamino)propyl]aluminum
• CAS: 199918-57-5
• 化学式: C₉H₂₁AlClN
• 分子量: 205.707
• InChiKey: LJEYFXCQIKZIBG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tert-butylchloro[3-(dimethylamino)propyl]aluminum 、 sodium azide 以 甲苯 为溶剂， 以56%的产率得到azido-tert-butyl[3-(dimethylamino)propyl]aluminum
  参考文献：
  名称：

  Syntheses and Structures of Intramolecularly Coordinated Azidoalanes

  摘要：

  The four intramolecularly coordinated azidoalanes R2Al(N-3) and RAltBu(N-3) (R = (CH2)(3)NMe2 (1b, 3b), 2-(Me2NCH2)C6H4 (2b, 4b)) were synthesized by reaction of the corresponding aluminum chlorides (1a-4a) with an excess of dry sodium azide in refluxing toluene or toluene/THF. The structures of the products were deduced from H-1, C-13, and Al-27 NMR spectra and were confirmed by X-ray structural determinations of la, Ib, and 2b. The compounds of type 1 and 2 contain pentacoordinated Al atoms, whereas the alanes of type 3 and 4 show tetracoordination of the central Al atoms.

  DOI：

  10.1021/om9706875
• 作为产物：
  描述：

  AlCl₂(DMP) 、 叔丁基锂 以 乙醚 为溶剂， 以81%的产率得到tert-butylchloro[3-(dimethylamino)propyl]aluminum
  参考文献：
  名称：

  Syntheses and Structures of Intramolecularly Coordinated Azidoalanes

  摘要：

  The four intramolecularly coordinated azidoalanes R2Al(N-3) and RAltBu(N-3) (R = (CH2)(3)NMe2 (1b, 3b), 2-(Me2NCH2)C6H4 (2b, 4b)) were synthesized by reaction of the corresponding aluminum chlorides (1a-4a) with an excess of dry sodium azide in refluxing toluene or toluene/THF. The structures of the products were deduced from H-1, C-13, and Al-27 NMR spectra and were confirmed by X-ray structural determinations of la, Ib, and 2b. The compounds of type 1 and 2 contain pentacoordinated Al atoms, whereas the alanes of type 3 and 4 show tetracoordination of the central Al atoms.

  DOI：

  10.1021/om9706875