| 12234-30-9

• CAS: 12234-30-9；648898-88-8
• 化学式: Br₁₂Mo₆
• 分子量: 1534.49
• InChiKey: ASRUVIJRDOBDOG-UHFFFAOYSA-B

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 在 sodium hydroxide 、 氢溴酸 作用下， 以 水 为溶剂， 生成 hydroxonium octa-μ3-bromo-hexa(bromo)octahedro-hexamolybdate(2-)
  参考文献：
  名称：

  Preparation of tetrabutylammonium octa-μ3-bromohexa(trifluoromethanesulfonato)octahedro-hexamolybdate (2−), (Bu4N)2[Mo6Br8i(CF3SO3)6a] and other derivatives containing the Mo6Br84+ core

  摘要：

  The compound (Bu4N)(2)[Mo6Br8i(CF3SO3)(6)(a)] (2), is prepared by the reaction of (Bu4N)(2)[Mo6Br8i(Br)(6)(a)] (1) and AgCF3SO3 in CH2Cl2. The triflate ligands, CF3SO3-, in compound 2 are readily substituted by other ligands, and convenient routes are reported for the preparation of the clusters [Mo6Br8i(X)(6)(a)](2-) where X = CF3CO2, SCN, NCO, Cl, Br and I. The preparation of the cationic cluster, [Mo6Br8i(Ph3PO)(6)(a)](4+), is also reported. The clusters were characterized by IR, UV-Vis, fluorescence and FAB mass spectrometry. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00027-9

文献信息

• Molybdenum and tungsten methoxo clusters with differently bonded methoxo groups
  作者：Nevenka Brničević、Ivan Bašic、Besnik Hoxha、Pavica Planinić、Robert E. McCarley

  DOI：10.1016/s0277-5387(03)00290-0

  日期：2003.6

  Abstract New molybdenum and tungsten methoxo clusters of the composition [M6(μ3-X)8X2(μ-OCH3)4/2]·2CH3OH (M=Mo, W; X=Cl, Br), [Mo6(μ3-X)8(OCH3)2(μ-OCH3)4/2]·CH3OH (X=Cl, Br) and [Na(CH3OH)5]2[Mo6(μ3-Br)8(OCH3)6] containing bridging (μ), both bridging and terminal, or terminal methoxo groups, respectively, have been prepared. The preparation procedures, spectroscopic and physical properties, including

  摘要组成[M6（μ3-X）8X2（μ-OCH3）4/2]·2CH3OH（M = Mo，W; X = Cl，Br），[Mo6（μ3-X） 8（OCH3）2（μ-OCH3）4/2]·CH3OH（X = Cl，Br）和[Na（CH3OH）5] 2 [Mo6（μ3-Br）8（OCH3）6]含桥接（μ）分别制备了桥基和端基或端基甲氧基。制备程序，光谱学和物理性质，包括X射线光电子能谱（XPS）已经相关联。[Na（CH3OH）5] 2 [Mo6（μ3-Br）8（OCH3）6]的晶体结构已经解析。该化合物在三斜晶系中结晶。该结构由两个[Na（CH3OH）5] +阳离子和[Mo6（μ3-Br）8（OCH3）6] 2-阴离子构成。